Environmental Protection Agency
Office of Environmental Enforcement (OEE)
Odour Emissions Guidance Note
(Air Guidance Note AG9)
September 2019
Environmental Protection Agency
Johnstown Castle Estate
Wexford, Ireland.
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All or parts of this publication may be reproduced without further permission,
provided the source is acknowledged.
Although every effort has been made to ensure the accuracy of the material contained in this
publication, complete accuracy cannot be guaranteed. Neither the Environmental Protection
Agency nor the authors accept any responsibility whatsoever for loss or damage occasioned
or claimed to have been occasioned, in part or in full, as a consequence of any person
acting, or refraining from acting, as a result of a matter contained in this publication.
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Contents
PREFACE ............................................................................................................................. 4
1.0 INTRODUCTION ....................................................................................................... 5
1.1 Descriptions Of Odour ............................................................................................ 5
1.2 Types Of EPA Licenced Facilities That Can Cause Odour ................................... 9
1.3 Sources Of Odour At These Facilities .................................................................. 10
2.0 ODOUR GUIDANCE OUTLINED IN BAT REFERENCE DOCUMENTS ................. 11
2.1 CWW BREF ............................................................................................................ 11
2.2 FDM BREF .............................................................................................................. 12
2.3 SA BREF ................................................................................................................ 13
2.4 WT BREF ................................................................................................................ 14
2.5 IRPP BREF ............................................................................................................. 14
3.0 ODOUR MANAGEMENT PLANS ........................................................................... 16
3.1 Odour Audit ........................................................................................................... 19
3.2 Odour Impact Assessment In Accordance With AG5 ......................................... 27
3.3 Modelling Of Odorous Emissions ........................................................................ 28
3.4 Appropriate Abatement Technologies ................................................................. 31
3.5 Methods Of Eliminating Odour (Including Fugitive Odour) ................................ 33
3.6 Minimisation Of Odours That Cannot Be Abated ................................................ 34
3.7 Odour Complaint & Investigation Procedure ...................................................... 35
3.8 Odour Management Plan Template ...................................................................... 37
4.0 SUMMARY OF ABATEMENT TECHNOLOGIES ................................................... 40
4.1 Appropriate Abatement Technologies ................................................................. 42
4.2 Management Of Abatement Systems ................................................................... 59
4.3 Monitoring Of Abatement Systems ...................................................................... 61
4.4 Maintenance Requirements Of Abatement Systems .......................................... 62
4.5 Staff Training Requirements ................................................................................. 64
5.0 TEST PROGRAMMES FOR ODOUR ABATEMENT EQUIPMENT ........................ 65
5.1 Monitoring Of Odour Abatement Effectiveness .................................................. 65
5.2 Template For A Test Programme ......................................................................... 66
5.3 Maintenance, Operation and Training to be Documented in Test Programme . 67
6.0 REFERENCES ........................................................................................................ 68
APPENDIX A Odour Complaint Report Form ............................................................... 69
APPENDIX B Odour Management Plan Checklist ........................................................ 70
APPENDIX C Test Programme Checklist ..................................................................... 71
APPENDIX D Glossary of Terms ................................................................................... 72
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PREFACE
One of the roles of the Environmental Protection Agency (EPA) is to contribute towards the maintenance
of a high-quality environment through ensuring that large scale industrial and waste activities which are
licensed by the EPA do not have an adverse impact on the environment and local community.
This Guidance Note (AG9 Odour Emissions Guidance Note) aims to provide clear and robust
methodologies for industrial and waste facilities in terms of odour abatement solutions that can be
implemented to reduce or eliminate odour. The document sets out recommended approaches for the
development of odour management plans, abatement strategies and test programmes and should allow
for improved consistency and reliability in addressing odour at industrial and waste facilities. This
guidance may also be useful for facilities which, although are not subject to EPA licencing, will be
required to control odour. Many measures, which are straight-forward, can be implemented at no or
minimal cost. For more serious odour problems, the selection of the correct abatement solution will be
critical.
An Odour Management Plan (OMP) is an essential tool for preventing, addressing and controlling odour
at an industrial or waste facility. The format of the OMP should provide sufficient detail to allow operators
and maintenance staff to clearly understand the operational procedures for both normal and abnormal
conditions at the facility. An OMP may be necessary prior to addressing requirements for abatement
and control or may be developed in tandem with the required control option.
A process design approach should be applied to the abatement selection process. Of fundamental
importance to selecting an odour abatement solution is that one must understand the fundamental
mechanism at work at the heart of the abatement technology and the chemistry of the molecules causing
the odour. This allows the licensee to select the abatement process which is most applicable to the
particular characteristics of the molecules requiring removal, transformation or destruction.
Once the abatement solution is selected, the site operator must demonstrate that the solution is suitable
and fit for purpose to meet the abatement targets set for the equipment. In order to demonstrate this, a
test programme will be required which details how the site operator proposes to prove the abatement
equipment’s suitability and capability to meet the abatement targets. The test programme shall enable
the site operator to assess the performance of any monitoring equipment on the abatement system. A
documented maintenance and calibration programme (including a schedule), for any monitor associated
with the abatement equipment, is also an essential part of the test programme.
It is hoped that this guidance will be of use to EPA and LA staff, operators and consultants in preparing
appropriate and effective odour abatement solutions to ensure licence compliance.
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1.0 INTRODUCTION
Uncontrolled odour from industrial and waste facilities can impact nearby communities and,
often, will lead to annoyance and a risk of ongoing complaints. Indeed, odour complaints
accounted for 40% of all complaints made to the EPA in 2017 (EPA, 2018). Odour is a priority
for the EPA and all licensees must ensure licence compliance.
In order to help address the issues surrounding unwanted odour in the ambient environment,
the EPA has produced this Guidance Note (AG9 - Odour Emissions Guidance Note). AG9
seeks to present a range of general principles and practical methods that may be used to
assess, control and abate odour from EPA licensed industrial and waste facilities.
The guidance document is primarily aimed at the responsible individuals at industrial and waste
facilities which will generally include environmental / environmental health & safety (EHS) /
general managers, engineers and operators. The guidance hopes to outline practicable
measures, many of which are straight-forward, which can be implemented at industrial and
waste facilities, to reduce or eliminate odour problems.
Prior to the completion of an odour abatement study and test programme, as part of a licence
application or review, it is recommended that the applicant discusses relevant aspects of the
project with the EPA prior to proceeding with the application process. Ensuring that a robust
abatement study and test programme is implemented prior to commissioning will help to ensure
that the proposed aim of an abatement project, namely a substantial reduction or complete
elimination of odour, is achievable.
The guidance, where necessary, has highlighted external references where more details on a
particular topic can be sourced.
1.1 Descriptions Of Odour
Human beings have the ability to sense certain molecules at very low concentrations via
sensory cells in the roof of the nose and then interpret specific molecules as producing a smell
or odour. The olfactory nerve sends stimuli to the brain which then identify the smell and decide
how to respond to this odour.
Where the odour is deemed to be offensive, unwanted or noxious, annoyance or frustration will
often be the individual’s response to odorous chemicals. Individual responses to odour are also
likely to vary depending on previous experience of the odour, the location of exposure and the
coping strategies of individuals. As outlined in Section 1.1.2, a range of perceived health
impacts may be experienced by individuals depending on the nature of the exposure.
Various descriptions of odour can be used with odour often being described by the EPA as
follows:
“A response of the olfactory receptor in the nose to certain types of volatile
chemicals present in the atmosphere’’, and
“The characteristic property of a substance which makes it perceptible to the sense
of smell”.
Many industrial and waste odours can be offensive or unpleasant and can lead to individuals
objecting to the presence of this odour in their environment.
Typically, industrial and waste facilities will have a licence condition which specifically states
that odour should not lead to significant impairment of, or significant interference with amenities
or the environment beyond the site boundaryor that the facility should not give rise to nuisance
at the facility or in the immediate area of the facility”.
Odours are the result of several properties of an odour which are experienced by a human
receptor. These properties can be summarised by the acronym “FIDOL” (which equates to
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Frequency, Intensity, Duration, Offensiveness and Location) as shown in Figure 1.1 and
described below:
Figure 1.1 FIDOL Factors Used To Determine Odour
The acronym FIDOL refers to the following factors:
Frequency of exposure how frequently is the odour detection (continuously,
intermittently, daily, infrequent)? The greater the frequency with which an odour is
experienced, the greater the likelihood that an odour will be deemed to be a nuisance.
Intensity of odour how strong is the odour (ranging from very faint to extremely
strong)? The sense of smell, like other human senses, is logarithmic and thus reducing
the concentration of an odour by a factor of two will have a much smaller perceived
reduction in intensity.
Duration of exposure how long does the exposure last (seconds, minutes, hours)?
Odour can be detected by the human nose over a very short period of time (a second
or less) but generally the longer the exposure the greater the risk an individual will
experience annoyance and frustration.
Offensiveness of the odour how pleasant is the odour (ranging from very pleasant
to very unpleasant)? Certain odours, such as hydrogen sulfide (rotten eggs) and methyl
mercaptan (rotten cabbage), will be objectional to almost everyone whilst other odours
are interpreted by most individuals as relatively pleasant (such as acetone (fruit)) or
limonene (lemon)). However, even pleasant odours, when experienced frequently, may
be unwanted and lead to complaints.
Location where was the odour experienced (residential, business, roadside, amenity
area)? When an offensive odour is experienced at an individual’s home or garden then
the risk of complaints will be greater than an odour which is detected whilst driving or
walking along public roadways. The surrounding land use may also factor into the
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individual’s interpretation of the odour. For example, all things being equal, a meat
processing facility located in a farming heartland may be more acceptable than a similar
facility located in a county town.
1.1.1 Constituents Of Odour
Odour is associated with either a release to air of an individual chemical compound or, more
typically, a complex mixture of chemical compounds which elicits an odour at a particular
concentration (referred to as the odour detection threshold for an individual compound).
Odour detection and interpretation is a complex process due to the range of confounding factors
as outlined in Box 1 (taken from Best Available Techniques (BAT) Reference Document for
Common Waste Water and Waste Gas Treatment/Management Systems in the Chemical
Sector (EC, 2016) (CWW BREF)):
Box 1 Confounding Factors Associated With Detection & Interpretation Of Odour
In combination with other substances, the characteristic odour of a single substance
can change.
Odour from a mixture of substances can change as the mixture becomes diluted and
the concentration of each substance, in turn, falls below its odour threshold.
Odours from a substance or a mixture can be pleasant when dilute but offensive
when concentrated.
At an industrial or waste facility, odours may be generated by a significant range of chemicals,
the most odorous of which include the following chemical groups with their characteristic odour
described in brackets:
Hydrogen sulfide (H
2
S) (rotten eggs) and
Organic Sulfides including dimethyl sulfide
(decaying vegetables), dimethyl disulfide
(putrid) and carbonyl sulfide;
Mercaptans including methyl mercaptan
(rotten cabbage) and propyl mercaptan
(unpleasant);
Volatile fatty acids including butyric acid
(rancid) and valeric acid (sweat);
Aldehydes and ketones including
formaldehyde (acrid) and acetone (fruit);
Nitrogenous compounds including
ammonia (pungent), skatole (faecal) and
indole (nauseating);
Amines including methylamine (fishy) and
ethylamine (ammonia-like).
The odour associated with a compound may change when combined with other odorous
compounds which may have a confounding effect on determining the general chemical structure
of the odorous compounds. This may have implications for the selection of the appropriate
abatement solution as the selection of the appropriate solution may vary depending on the
chemical structure and properties (such as the degree of hydrophobicity) of the odorous
releases.
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1.1.2 Impacts Of Odour on Health and Well-being
Studies have investigated the possible link between odour exposure and a variety of impacts
on health and wellbeing (Horton, 2009), (Schinasi, 2011), (Heaney, 2011). Research has found
some evidence that odour can lead to a range of physical, psychological and social health
impacts.
Physical health impacts that may be linked to odour exposure include (Heaney, 2011),
(Schinasi, 2011), (Alliance, 2015):
Nausea,
Reduced appetite,
Congestion,
Sensory & respiratory irritation,
Headaches,
Dizziness,
Sleep problems.
It is unclear whether the odours directly or the stress associated with exposure to these odours
leads to the physical symptoms.
Psychological effects have also been linked with odour exposure in some studies. The
symptoms reported include (Horton, 2009), (Heaney, 2011), (Alliance, 2015):
Tension,
Nervousness,
Anger,
Frustration,
Depression,
Fatigue,
Confusion,
General stress.
The psychological responses may be due to health worries associated with the exposure or the
stress associated with the feeling that their odour concerns are not being heard. Psychological
effects have also been found to lead to physical effects i.e. stress experienced by odour
exposure has been linked to higher blood pressure in individuals (Alliance, 2015).
Social wellbeing has also been found to be impacted by odour. Some studies have found that
odour may decrease the quality of life including (Tajik, 2008), (Alliance, 2015):
Decreased outdoor activities,
Keeping windows shut,
Being forced to leave home due to odour,
Decreased property value,
Embarrassment leading to decreased social interaction.
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1.2 Types Of EPA Licenced Facilities That Can Cause Odour
Examples of EPA licenced facilities which can potentially cause odour in the absence of the
necessary odour controls and abatement measures are outlined below. This list is however not
exhaustive:
Industrial and waste facilities with
onsite Wastewater Treatment
Plants (WwTPs) sources include
primary settlement / balancing tanks
and the resultant sludge treatments.
Anaerobic Digestion raw material
odours and tanker transfer of
digestate are potential issues.
Intensive Agriculture poultry litter
and pig manure can lead to odours.
Animal By-products all stages of
the treatment of animal by-products
should be viewed as high risk.
Composting Facilities potentially
odorous activities include turning
activities in the open air.
However, any industrial and waste facility using or producing odorous material has the potential
to create an odour in the absence of appropriate controls.
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1.3 Sources Of Odour At These Facilities
The main sources of odour at the facility types outlined in Section 1.2 include the following:
Emission stacks;
Ineffective abatement systems;
Storage of animal by-products;
Waste storage and treatment areas;
Cooking and boiling release points;
Transferring of materials / loading /
unloading of odorous material.
Industrial wastewater treatment
plants including the following
activities:
Primary settlement,
Balancing tanks,
Sludge holding tanks,
Sludge dewatering,
Sludge thickening / digestion;
Odour may however arise at any location where odorous material is present via fugitive releases
(building leaks, seals, pressure relief valves) or operator error (leaving doors open, spills, leaks
etc). As outlined in Section 3, all potential odour release points should be reviewed by means
of a detailed site audit and any risks that are identified should be mitigated.
In subsequent sections, this Guidance Note will focus on the following topics:
A review of BAT Reference Documents applicable to odorous industries (Section 2);
Guidance on preparing an Odour Management Plan (Section 3);
A review of abatement technologies and the approach necessary to determine the
most appropriate abatement solution for a facility (Section 4);
Guidance on preparing a test programme for the proposed abatement solution
(Section 5).
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2.0 ODOUR GUIDANCE OUTLINED IN BAT REFERENCE DOCUMENTS
The EU has produced a range of vertical (sectoral) BAT Reference Documents (BREFs) and
several horizontal (i.e. applicable across sectors / industries) BREFs over the last decade or
more. The process is ongoing with many older BREFs currently undergoing revisions and
additional sectors currently being drafted. A review of relevant BREFs relating to odour is
discussed below and includes the following BREF documents:
Relevant BREF Documents
BAT Reference Document for Common Waste Water and Waste Gas
Treatment/Management Systems in the Chemical Sector (EC, 2016) (CWW BREF),
BAT Reference Document in the Food, Drink and Milk Industries (EC, 2018) (FDM
BREF),
Reference Document on Best Available Techniques in the Slaughterhouses and Animal
By-products Industries (EC, 2005) (SA BREF),
Best Available Techniques (BAT) Reference Document for Waste Treatment (EC, 2018)
(WT BREF),
Best Available Techniques (BAT) Reference Document for the Intensive Rearing of
Poultry or Pigs (EC, 2017) (IRPP BREF).
2.1 CWW BREF
Commission Implementing Decision (EU) 2016/902 established the BAT Conclusions for The
Common Waste Water and Waste Gas Treatment Management Systems in the Chemical
Sector (EC, 2016). The Decision confirms that BAT, to prevent or where not practicable reduce
odour, is to implement and regularly review an OMP as part of the facility environmental
management system. The OMP should include all of the following elements:
I. a protocol containing appropriate actions and timelines;
II. a protocol for conducting odour monitoring;
III. a protocol for response to identified odour incidents;
IV. an odour prevention and reduction programme designed to identify the source(s); to
measure / estimate odour exposure; to characterise the contributions of the sources;
and to implement prevention and / or reduction measures.
The Decision also confirms that odour monitoring should be conducted in accordance with
EN13725:2003 Air Quality Determination of Odour Concentration by Dynamic Olfactometry
with the option to complement this monitoring by measurement / estimation of odour exposure or
estimation of odour impact.
The CWW BREF outlines a range of techniques considered BAT. To reduce emissions from
waste water collection and treatment and from sludge treatment, one or a combination of the
techniques outlined below should be used:
Minimise the residence time of waste water and sludge in collection and storage systems,
in particular, under anaerobic conditions.
Use chemicals to destroy or to reduce the formation of odorous compounds (e.g.
oxidation or precipitation of hydrogen sulfide).
Optimise aerobic treatment. This can include:
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i. controlling the oxygen content;
ii. frequent maintenance of the aeration system;
iii. use of pure oxygen;
iv. removal of scum in tanks.
On a case by case basis, cover or enclose facilities for collecting and treating waste water
and sludge to collect the odorous waste gas for further treatment.
End-of-pipe treatment. This can include:
i. biological treatment;
ii. thermal oxidation.
The BAT Reference Document for Common Waste Water and Waste Gas
Treatment/Management Systems in the Chemical Sector (EC, 2016) (CWW BREF) outlines
specific techniques and technologies which would currently be considered BAT for reducing
odour.
Some general issues identified in terms of the formation of odours include:
The importance of controlling
sulphate in the influent of WwTPs due
to the potential to form hydrogen
sulfide.
Nitrogen compounds can also lead to
issues at WwTPs where they
breakdown into ammonia and amine.
WwTPs should seek to optimise the
aerobic treatment, e.g. by controlling
the oxygen content, frequent
maintenance of the aeration system,
use of pure oxygen and / or removal
of scum in tanks.
Fugitive / diffuse emissions should be
prevented through proper design of
storage and handling facilities and
through seals on pumps.
The CWW BREF includes the following recommendations in relation to biofilters:
For biofilters, the media pH, media depth, moisture content and inlet gas temperatures
will affect odour removal capacity.
The residence time for effective abatement of odour through the biofilter should, as a
rough guide, typically be a minimum of 30 45 seconds, with ranges of 25-60 seconds
also commonly noted.
2.2 FDM BREF
The BAT Reference Document in the Food, Drink and Milk Industries (EC, 2018) (FDM BREF)
summarizes a range of practicable measures which will help to reduce the odour impact from
these facilities:
Odour control should be based on a four-stage strategy, the extent to which each stage
needs to be applied being site-specific:
Defining the problem determine whether odour problems exist based on the
number and frequency of odour complaints.
Develop an inventory of site odour emissions the sources should be ranked
in terms of the severity of their impact on the surrounding environment.
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Undertake an odour emission monitoring survey based on dynamic
olfactometry. Air dispersion modelling may also be required to determine
whether odour control is necessary.
Select the appropriate air emission control technique this may involve
process-integrated treatment (i.e. substance substitution, low emission
systems) and / or end-of-pipe treatment (abatement system of appropriate
efficiency / effectiveness).
Segregation of animal by-products will help to reduce cross-contamination and potential
odour problems whilst helping to reduce the volume of mixed by-products. This will
also allow all products to be disposed of in the most appropriate way.
The FDM BREF outlines the range of techniques which are frequently used to reduce
organic / odour emissions in the Food and Drink sector:
Wet scrubber;
Plate absorber;
Adsorption;
Bio-filter;
Bio-scrubber;
Thermal oxidation;
Catalytic oxidation;
Non-thermal plasma treatment;
Extending the height of the discharge stack;
Increasing the stack discharge velocity;
Use of UV / ozone in absorption (emerging technique);
Odour Management Plan (OMP).
The FDM BREF also notes in terms of an OMP that a review of historical odour incidents and
remedies and the dissemination of odour incident knowledge should be undertaken.
2.3 SA BREF
The Reference Document on Best Available Techniques in the Slaughterhouses and Animal
By-products Industries (EC, 2005) (SA BREF) describes a number of practicable measures, in
line with BAT, which can be employed to reduce emissions as outlined in Box 2:
Box 2 Measures outlined in the Slaughterhouses and Animal By-products
Industries BREF (EC, 2005) (SA BREF)
Odour problems can be minimised by co-operation between the slaughterhouse and
the animal by-products installation. If the handling and storage of by-product at the
slaughterhouse is not focused on minimising odour, the animal by-product facility will
likely have odour issues even if the animal by-product is treated immediately upon
arrival.
Where it is not possible to treat animal by-products before decomposition starts to
cause odour problems, refrigerate them as quickly as possible and for as short a
time as possible prior to processing.
Where inherently odorous material is used or produced during the treatment of
animal by-products, pass the low intensity / high volume gases though a biofilter.
Non-condensable gases should be passed through an existing boiler with pure
vapour gases treated in a thermal oxidiser.
The segregation of by-products can reduce potential odour problems from those
materials which even when fresh emit very offensive odours.
Although not a BAT requirement, odour benefits arise from the cooling of blood to below 10°C.
A pilot plant investigation found that the odour concentration increased by a factor of 60 when
the storage temperature was increased from 4°C to 30°C.
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2.4 WT BREF
The Best Available Techniques (BAT) Reference Document for Waste Treatment (EC, 2018)
(WT BREF) outlines a number of practicable measures which can be employed to reduce
emissions as outlined in Box 3:
Box 3 Practicable Measures Outlined In The Waste Treatment BREF (EC, 2018)
Odour criteria should be applied to reject biodegradable wastes that are already
releasing or have the potential to release mercaptans or VOCs, low molecular weight
amines, acrylates, or other similarly highly odorous materials that are only suitable
for acceptance under special handling requirements.
Minimise the residence time of potentially odorous waste in collection, storage and
handling systems (e.g. pipes, tanks, containers), in particular, under anaerobic
conditions (when relevant, adequate provisions are made for the acceptance of
seasonal peak volumes of waste).
Use chemicals to destroy or to reduce the formation of odorous compounds.
Optimise the aerobic treatment, e.g. by controlling the oxygen content and frequent
maintenance of the aeration system. In the case of aerobic treatment of water-based
liquid waste, the optimisation may also include the use of pure oxygen and/or
removal of scum in tanks.
On a case by case basis, cover or enclose facilities for storing, handling, collecting
and treating odorous waste (including waste water and sludge) and collect the
odorous waste gas for further treatment.
End-of-pipe treatment.
Where the waste storage area is in an enclosed building, there should be a building
ventilation system and an emission abatement system that maintains the building
under a negative air pressure in order to minimise fugitive odour.
2.5 IRPP BREF
Commission Implementing Decision (EU) 2017/302 established BAT Conclusions, Under
Directive 2010/75/EU, for The Intensive Rearing of Poultry or Pigs (EC, 2017). The Decision
confirms that BAT, to prevent or where not practicable reduce odour emissions, is to implement
and regularly review an OMP as part of the facility environmental management system.
The Best Available Techniques (BAT) Reference Document for the Intensive Rearing of Poultry
or Pigs (EC, 2017) (IRPP BREF) document outlines good operational practice for both pig and
poultry housing which will reduce odour including:
Cleanliness: Pigs and poultry should be kept clean of manure whilst reducing the
exposed area of manure and avoiding spilled feed will reduce odour emissions.
Dryness: Keeping the lying and activity area dry will reduce odour emissions.
Slurry removal: Pig manure should be removed to storage pits or subject to an
appropriate treatment, including land-spreading, as quickly as practicable to avoid
increased odour emissions.
Optimise the discharge conditions of exhaust air from the animal house by using
one or a combination of the following techniques:
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Increasing the outlet height (e.g. exhaust air above roof level, stacks, divert air
exhaust through the ridge instead of through the low part of the walls);
Increasing the vertical outlet ventilation velocity;
Effective placement of external barriers to create turbulence in the outgoing air flow
(e.g. vegetation);
Adding deflector covers in exhaust apertures located in low parts of walls in order
to divert exhaust air towards the ground;
Dispersing the exhaust air at the housing side which faces away from the sensitive
receptor;
Aligning the ridge axis of a naturally ventilated building transversally to the
prevailing wind direction.
Using an air cleaning system, such as:
Bio-scrubber,
Bio-filter,
Two-stage or three-stage air cleaning system.
Guidance on the storage of slurry to reduce odour emissions includes, where appropriate:
Covering of slurry or solid manure during storage;
Take prevailing wind direction into account in locating the store and / or adopt measures
to reduce the wind speed around and above the building;
Minimise the stirring of slurry (turbulence, due to stirring, can increase emissions ten-
fold compared to a still surface);
Reducing the effective surface area relative to the volume of manure will reduce the
odour emissions i.e. manure can be compacted, or a three-sided wall can be
constructed.
Manure land-spreading guidance suggests that the following points should be considered prior
to spreading:
Avoid spreading when people are likely to be at home, unless it is absolutely necessary;
Pay attention to wind direction in relation to neighbouring houses;
Avoid spreading in warm humid conditions;
Use spreading systems which minimise the production of dust or fine droplets;
Cultivate land as soon as possible after land-spreading.
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3.0 ODOUR MANAGEMENT PLANS
Odour management at a licenced facility should be proactively undertaken and be viewed as a
necessary requirement alongside, and in addition to, the requirement to avoid causing odour.
Facilities should not await complaints before implementing an odour management plan but
rather should view the plan as a preventative measure which helps ensure complaints do not
arise in the first place.
Odour management conditions which are currently included in licences issued by the EPA
(Industrial Emissions (IE), Integrated Pollution Control (IPC) and Waste Licences) will normally
include a section on implementing an odour management plan similar to the following example:
Odour Management Plan (OMP) Requirements (Example Text):
The licensee shall, within one year of commencement of the Scheduled Activity,
submit an odour management programme for agreement by the Agency outlining
current odour reduction measures appropriate for the site. The licensee shall
implement this odour management programme with the agreement of the Agency,
within a specified timeframe. The odour management programme shall be reviewed
annually, and amendments thereto notified to the Agency for agreement as part of the
Annual Environmental Report (AER). A report on the programme shall be prepared
and submitted to the Agency as part of the AER.
The licensee shall undertake, as required by the Agency, an odour assessment which
shall include as a minimum the identification and quantification of all significant odour
sources and an assessment of the suitability and adequacy of the odour abatement
systems to deal with these emissions. Any recommendations arising from such an
odour assessment shall be implemented”.
An OMP is an essential tool for preventing, addressing and controlling odour at an industrial or
waste facility. The format of the OMP should provide sufficient detail to allow operators and
maintenance staff to clearly understand the operational procedures for both normal and
abnormal conditions at the facility. The OMP should be:
Non-Complex: the plan should aim to be as straightforward as possible while still
addressing all the necessary control measures and preventative actions.
Structured & Systematic: there should be a clear logic to the layout of the plan which
makes it easy to navigate and implement.
Identify Responsibility: the plan should allow the relevant onsite personnel to know
who is responsible for implementing each task outlined in the plan in a step-by-step
manner.
Detailed information and examples of odour management plans have been formulated by,
amongst others, legislators in the UK (DEFRA, 2010), (SEPA, 2010)), (EA, 2011), Australia
(NSW, 2006), New Zealand (NZMFE, 2016) and professional bodies (IAQM, 2014). These
resources have many common elements although the details vary from author to author.
Ownership of the OMP should be identified with the nominated personnel, who has overall
responsibility for implementing and updating the plan on an on-going basis, outlined. The
person(s) with responsibility for the OMP should keep full records of all inspections, checks,
surveys, complaints and corrective actions relating to the OMP and odour issues in general.
The OMP is a living, working document which should explain and outline how the facility will
manage odour generation and prevent or minimise odour. The OMP should form part of the site
standard operating procedures and / or be integrated into their Environmental Management
System (EMS) with regular review cycles. As such, when developing an OMP, the approach
should adopt a similar approach used in the change management process such as the
ISO:14001 Plan-Do-Check-Act (PDCA) Cycle as shown in Figure 3.1.
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Figure 3.1 Adoption and Implementation of an Odour Management Plan (OMP)
Key aspects of an odour management plan which, when incorporated into an environmental
management system, would be considered BAT (adapted from the FDM BREF (EC, 2018) are
shown in Box 4 (and shown graphically in Figure 3.2):
Box 4 Key Aspects Of An OMP (taken from FDM BREF (EC, 2018))
Commitment of the management, including directors and senior management;
Definition, by the management, of an odour management policy, that includes the
continuous improvement of the environmental performance of the installation;
Planning and establishing the necessary procedures, objectives and targets;
Implementation of procedures paying particular attention to:
o Structure and responsibility;
o Recruitment, training, awareness and competence;
o Communication and employee involvement;
o Documentation;
o Effective process control;
o Maintenance programmes;
o Emergency preparedness and response;
o Safeguarding compliance with environmental legislation;
Checking performance and taking corrective action, paying particular attention to:
o Monitoring and measurements;
o Corrective and preventative action;
o Maintenance of records;
o Auditing in order to determine whether the OMP has been properly
implemented and maintained;
Review, by senior management, of the OMP and its continuing suitability,
adequacy and effectiveness.
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The OMP should outline in detail how
all odour sources onsite will be
managed and controlled on an
ongoing basis. The OMP should also
identify possible abnormal operational
occurrences and reasonably
foreseeable accidents / incidents.
The plan should then address in a
step-by-step basis how these
abnormal operation events will be
rectified in as short a period of time as
possible.
Figure 3.2 Odour Management Plan Principle (Based on FDM BREF (EC 2018))
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3.1 Odour Audit
An extensive site audit is an
essential first step in determining
the key odour sources at a facility
and, where necessary, in
controlling and abating odour to
ensure no odour occurs beyond
the site boundary.
The audit should ensure that the
baseline conditions for a facility
are known as accurately as
possible. Audits also serve as an
effective preventative tool which
can avert odour being generated
in the first place.
For example, if the odour emission rate is unknown for a range of odour sources it may be
necessary to quantify the odour emission rates from these sources using dynamic olfactometry
monitoring based on European Standard EN13275:2003 Air Quality Determination of Odour
Concentration by Dynamic Olfactometry”. The method involves the use of the lung” principle
where odorous air is drawn into a sampling bag which has been placed within a rigid container.
A vacuum pump is used to create a negative pressure within the container with the sampling
bag expanding to fill the vacuum with the odorous air. Thereafter, the sample is measured
based on the number of dilutions required to reach the detection threshold based on a panel of
at least four people with a normal sense of smell. The number of dilutions required is called the
“odour concentration” and has units of OU
E
/m
3
.
Shown in Figure 3.3 is a brief overview of the steps which are required to undertake a
successful site audit. The potential impact of odour from the sources at the facility can be
determined from a review of the type, magnitude, environmental impact and frequency of
operation of the process. The personnel conducting the audit should fully understand the
process from receipt of raw materials, through all stages of production to off-site removal of
product or disposal / recovery. A process flow diagram such as the examples shown in Figure
3.4 and Figure 3.5 will help to identify and isolate the key odour sources for further investigation.
The site audit should also be undertaken with an awareness of the sensitivity of the surrounding
environment. The personnel undertaking the audit should be fully aware of the location of all
nearby sensitive receptor locations including residential receptors, schools, commercial
premises, amenity areas and hospitals. The facility should have a complaints procedure in
place as part of the site odour management plan (as outlined in Section 3.7). The complaints
log should be investigated as part of the site audit to determine whether there have been any
recent complaints and to determine if the source of these complaints has been identified or if
the activities at the time of the complaint can be determined. The complaints log can be useful
in directing the audit to the most high-risk areas i.e. those sources and activities which are
causing annoyance in the local community.
The site audit should identify all potential odour sources in terms of the following categories and
attribute a risk rating to them (high, medium or low risk sources):
Raw Materials: raw materials of concern from an odour perspective will generally be
solids or liquids which have the potential to release odorous volatile organic
compounds. Particular care should be paid to any material which is open to atmosphere
or might be released from diffuse or fugitive sources. Some facilities will have high risk
material that will inevitably lead to odour generation, such as the handling of organic
and putrescible waste at waste transfer / composting facilities whilst other sources may
be of a lower risk and may be odorous only under unfavourable conditions (primary
settlement tanks at industrial WwTPs where the influent has become anaerobic, for
example).
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Equipment: equipment, particularly where there is an interface to atmosphere such as
valves, release points, openings for filling / emptying of materials, are a potential source
of odour. It is likely there will be a range of odour sources which have the potential to
generate odour, some of which will be of greater concern than others.
Processes & Activities: the audit should review the processes and activities which are
undertaken and evaluate whether any of the activities can be altered such that odour
generation is minimised. For example, for a waste handling facility, the age of the waste
should be minimised to avoid anaerobic conditions whilst the surface area of waste
exposed to atmosphere should also be reduced to avoid odour release.
Figure 3.3 Site Odour Audit Flowchart
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Release points: the audit should identify all major emission points such as stacks /
area sources with the potential to emit odorous material. Potential or minor emission
points should also be investigated as possible odorous sources including passive vents
and pressure relief valves.
Finished Product / Waste: Depending on the activity, the finished product or waste
may be odorous. Abattoirs will produce animal by-products which will quickly decay
and cause odour issues if not controlled properly whilst industrial WwTPs will have
sludge as a waste which may be odorous depending on the treatment method. Waste
transfer facilities and MBT (mechanical & biological treatment) facilities may generator
SRF (solid recovered fuel) or RDF (refused-derived fuel) which may be odorous if
exposed to atmosphere or stored onsite for long periods.
Deliveries / Export: If odorous material is delivered to the facility or exported from the
facility, odour may occur if materials are not fully sealed. Risks associated with this
activity will be greatest for situations where there are static sources such as queuing of
trucks to off-load odorous material.
The category Process and activities is generally the most critical aspect of the audit and
requires the most time and resources to ensure that the audit is undertaken successfully. Each
identified process or activity should be isolated, and each relevant source assessed for odour
risk with a determination made as to whether there is a need for a more detailed assessment to
be undertaken.
Figure 3.4 Example Process Flow Diagram Identifying Key Potential Odorous Sources
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Figure 3.5 Example Process Flow Diagram Waste Transfer Station
3.1.1 Detailed Assessment Of Odour Pathways
Based on the initial audit, high risk sources may need to be investigated in detail. There are a
range of tools which can be employed to determine the significance of the identified high-risk
sources. The tools which can be employed when undertaking a more detailed assessment
include:
Quantification of the odour sources onsite using dynamic olfactometry measurements
in line with EN13725:2003 Air Quality Determination of Odour Concentration by
Dynamic Olfactometry;
Air dispersion modelling of the measured odour samples in the ambient environment
beyond the site boundary (as outlined in Section 3.3);
A review of the frequency and geographical spread of the predicted odour concentration
from each onsite source;
Each source should be quantified (on a time-weighted basis) to determine their
significance, thus allowing the audit to focus on the most significant sources.
Where necessary, modelling of the proposed abatement / process improvement
technique should be undertaken to assess whether the proposed solution will be
effective; and
Assessment of post-abatement odour levels in the environment and comparison with
odour guideline levels should be conducted. A review of the odour complaints record
should also be undertaken to ensure that the abatement solution has been effective.
At facilities with existing odour complaints, a multi-tool approach involving the full range of
approaches outlined above may be necessary to determine the root cause of the odours. Only
by identifying the root cause of the complaints will it be possible to determine the appropriate
control or abatement solution required for the resolution of the problem.
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3.1.2 Inventory Of Materials
The determination of odorous sources and streams should start with materials which are
imported to site which may include raw materials for processing (in the case of the food and
drinks industry, generic industrial facilities), waste to be treated (in the case of the waste
industry, rendering) or, in some cases, living animals (intensive agriculture).
The inventory should be reviewed to determine if procedures can be implemented which will
reduce odour at source such as:
Capacity The amount of material accepted into a facility should be no greater than
the capacity of the facility to treat in a timely manner. As an example, a waste transfer
station should have a policy of only accepting waste that can be treated within a defined
period (for example 24 or 48 hours) to avoid the risk of anaerobic conditions developing.
Thus, operators should have a knowledge of the maximum throughput that the facility
can process in any one day and have a policy in place to divert waste above the
capacity threshold of the facility.
Screening A screening policy for incoming materials will normally be conditioned as
part of the Licence for the facility to ensure that the material is not contaminated with
particularly odorous impurities or has deteriorated beyond an acceptable standard.
Procedures should be put in place with suppliers which allows materials to be rejected
when standards are breached.
Storage The storage of imported materials should be reviewed from the point of view
of odour generation. Odour will tend to increase from materials which are:
exposed to the atmosphere (from evaporation of odorous compounds),
during periods of high ambient temperatures which increases the rate of
volatilisation,
when it is agitated (in the open air), and
where the material has a large surface area exposed to atmosphere.
Thus, reductions in odour generation can be gained by:
Reducing the exposure of materials to atmosphere by storing within a building
or installing windbreaks / barriers where material needs to be stored outdoors;
Ensure materials are not in direct sunlight either by storing within buildings or
in shaded areas of the facility;
Keeping the exposed surface area to a minimum and restricting agitation of
materials to a minimum;
Materials should be stored under negative pressure wherever possible with the
odorous air extracted for treatment if necessary;
Doors should be close-fitting and kept closed at all times with self-closing
mechanisms installed;
Misting of materials can reduce temperatures and increase relative humidity
thus reducing evaporation;
Waste being stored in accordance with the site’s waste storage plan.
3.1.3 Processes And Activities
The processes and activities which are undertaken by the facility should be analysed to identify
when and where in the process odour could potentially be released to atmosphere. The key
considerations include:
Temperature Heating or cooking processes are likely to be a significant source of
volatile organic compounds releases into the atmosphere including odorous
compounds. High ambient temperatures will also increase chemical reactions in
general which increases both the volatility of organic compounds and the risk of
anaerobic conditions.
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Pressure A positive pressure in the system will lead to the risk of fugitive releases. If
possible from a process viewpoint, creating a small negative pressure differential will
decrease the potential for fugitive releases.
Building Integrity Many odorous processes or activities are undertaken within
buildings with a negative pressure system installed to reduce fugitive emissions. For
negative pressure systems to work effectively the integrity of the building should be
sufficient to ensure effective containment of odours. Even without a negative pressure
system in place, where buildings are used to store odorous material, a system should
be in place with frequent checks to ensure that there are no gaps or cracks in the
structure of the building. A smoke test (based on ASTM standards E1186 / E741) may
be required in order to identify any leakages prior to remedial action. An air lock system
may be necessary where highly odorous sources are exposed within a building.
Ventilation Many processes or activities at industrial and waste facilities may require
a ventilation system be installed on health and safety grounds (rather than purely for
odour abatement considerations). However, where this occurs it can also have a
positive impact on odour. Where there is a ventilation system under negative pressure,
the air stream can be extracted and directed to a stack for dispersion in the surrounding
environment. Depending on the initial odour concentration and the volume of air
exchanged, odours may be sufficiently diluted by this method alone and require no
further treatment. Alternatively, the odour may be of sufficient magnitude to require an
abatement system prior to release from the stack. Air dispersion modelling is normally
required to confirm whether additional abatement is necessary in these circumstances.
3.1.4 Equipment
Equipment may release odour intentionally, via specific emission sources (pressure release
valves, passive venting), or unintentionally via leaks due to fugitive releases from valves, seals,
flanges etc particularly where the system is under positive pressure. Where necessary, a
fugitive emission study of the facility should be undertaken using ISO EN 15446:2008 “Fugitive
and Diffuse Emissions of Common Concern to Industry Sectors Measurement of Fugitive
Emission of Vapours Generating from Equipment and Piping Leak with a corrective action plan
implemented promptly. Passive vents and pressure relief valves may be important depending
on the frequency of operation and the associated odour emission rate of these sources. Where
it is found that these sources are contributing to off-site odour complaints, corrective engineering
solutions should be investigated.
3.1.5 Release Points
A release point may be an emission point such as a stack or a less contained source such as
an area or volume source (aeration basin, tank, weir). When releasing an odour through a stack
it is important that the exit conditions are sufficient to escape the building wake and to avoid the
risk of plume recirculation in the cavity zone adjacent to the building on which the stack is
located. Generally, it is desirable to achieve an exit velocity of greater than 10 - 15 m/s based
on a vertically positioned stack and with no obstacles (such as rain caps) to interrupt the
mechanical and / or buoyancy driven plume rise.
Where it is found that existing stacks are creating an odour offsite, it may be necessary to
increase the stack height by means of a stack height optimisation study using air dispersion
modelling. Alternatively, abatement may be required to reduce the odour emission rate
sufficiently to avoid odour detection offsite. It is also possible that a combination of a stack
height increase, and a less efficient (but cheaper / more practicable) odour abatement solution
may be preferred to achieve the same optimised solution.
Area and volume sources will generally benefit from restricting evaporation of the liquid / solid
surface. Thus, measures which reduce evaporation will be beneficial such as restricting
turbulence, covering of sources to reduce wind flow over the surface and maintaining a low
temperature will all be beneficial from an odour release perspective.
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3.1.6 Staff Training Requirements
In order for site audits and odour
management plans to be
undertaken and implemented
effectively, there will be a
requirement for all staff
members to be adequately
trained. The training should be
adapted to suit the tasks and
responsibilities of the relevant
personnel and the odour risk
profile of the facility including the
sensitivity of the surrounding
environment.
Training requirements should include the following:
How and why odour is controlled and the importance of the control measures which are
in place in ensuring that odour impacts are prevented or, at least, minimised should be
explained to relevant personnel.
General good housekeeping practices should be covered in the training programmes
including site maintenance, record keeping, inventory and product storage.
Staff should be trained in the odour management procedures to be implemented under
circumstances where abnormal operation / emergencies onsite occur.
All environmental incidents with the potential for odour release such as spills, leaks and
failure of equipment should be documented and recorded in the OMP file. A follow-up
note should address the root cause of the incident and include a discussion of the
measures introduced to prevent a reoccurrence.
Relevant staff members should be aware of the procedure to deal with odour
complaints.
Staff should be trained to undertake site odour impact assessment in line with EPA
publication AG5 Odour Impact Assessment Guidance for EPA Licensed Sites (AG5)
(EPA, 2019).
Staff should be trained in the Source-Pathway-Receptor concept and thus
understand how the release of odour onsite can lead to an odour at nearby receptors
(Figure 3.6).
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Figure 3.6 Odour Source-Pathway-Receptor Concept
Particular attention should be paid to the following issues affecting the source of the odour:
Facilities with highly odorous compounds with very low odour detection
thresholds (e.g. mercaptans) are at a greater risk of odour.
Operators of processes with a large volume of unpleasant odours (e.g.
rendering) will need to be keenly aware of any potential release points.
The larger the facility in terms of tonnage of material, the greater the risk to the
immediate environment.
Facilities with external odour sources and an absence of abatement will require
a higher degree of active controls to ensure odour release is minimised.
The factors affecting the pathway include:
The distance from each source to each receptor with extra vigilance required
for high sensitivity receptors such as residential receptors.
The meteorological conditions in particular the frequency of wind blowing
towards receptors and the occurrence of low wind speeds.
The topography between the sources and receptors (e.g. a downwards sloping
valley between source and receptor may intensify the impact).
The selection of stack height, exit velocity, and temperature of release for
odours released from stacks.
The factors affecting receptor sensitivity include:
High sensitivity receptors include residential homes, hospitals, nursing homes,
creches, businesses (retail/commercial), industry and schools within the area
of the observation point. Facilities with the potential for odorous emissions
located close to these receptors will generally require a high degree of odour
control.
Moderate sensitivity locations will have housing, commercial/industrial or public
areas within 100m of the observation point.
Low sensitivity locations will have housing, commercial/industrial or public
areas between 100m 500m of the observation point.
Remote sensitivity locations will have no housing, commercial/industrial or
public areas within 500m of the observation point.
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3.2 Odour Impact Assessment In Accordance With AG5
The assessment of odour from the facility should be undertaken using the procedures and
guidelines outlined in EPA publication AG5 Odour Impact Assessment Guidance for EPA
Licensed Sites (AG5) (EPA, 2019) and described below in Box 5. The assesment involves the
use of an odour impact assessment at suitable locations in the vicinity of a facility. Odour impact
assessment is the use of the human nose to assess odour and is the most common form of
odour monitoring in the field. The procedure requires that the odour impact assessment is
applied in a consistent and systematic way, the details of which are outlined in AG5. When
properly undertaken on a regular basis, the results of odour impact assessments can be used
to support, or otherwise, the evidence of complaints by members of the public.
Box 5 Odour Impact Assessment Protocol
An offsite odour impact assessment at nearby sensitive receptors should form part of the
odour audit. The odour impact assessment should take the following factors into account:
Staff should only undertake the odour impact assessment prior to coming to work
as staff are likely to be desensitised to the odour generated onsite, termed odour
adaptation, and thus might be unable to objectively assess odour in the
surrounding environment.
Prior to the test, the wind conditions must be confirmed, and an initial odour impact
assessment taken upwind of the facility prior to moving to downwind locations.
The survey should be undertaken using the “Assessment of Odour Impact Field
Record Sheet (Annex A) which is an annex to AG5 (EPA, 2019). The survey
should record both the intensity of the odour and its persistence at each location
assessed using the terminology outlined in Figure 3.7.
The personnel undertaking the survey should not smoke, chew gum, drink coffee /
tea nor be experiencing a medical condition (such as a cold / flu) which could
interfere with the test.
Surveys should be conducted on at least several occasions over varying days of
the week. The time of day when odour complaints are made and the wind direction
which leads to most complaints should be considered also.
The surveys should also be ideally undertaken at different times of the day and
under a range of weather conditions.
Where an odour is detected, an inspection of the facility must be carried out directly
by the odour investigator, to determine whether any observed odour can be linked
to the site and to evaluate any potential odour producing activities or locations.
Understanding the actual process conditions onsite at the time of the complaint will
help to locate the issue and isolate the problem.
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Figure 3.7 Odour Intensity & Offensiveness Scale Terminology
3.3 Modelling Of Odorous Emissions
The air dispersion modelling of odour from a facility should be undertaken using the procedures
and guidelines outlined in EPA publication AG4 Air Dispersion Modelling from Industrial
Installations Guidance Note (AG4)(EPA, 2010). A short summary of the pertinent issues is
outlined below.
Firstly, there are two general approaches to assessing odour emission rates from industrial
installations. One approach is to assess the emissions from the installation in terms of Odour
Units (OU or OU
E
/m
3
). A second approach is to use a chemical marker which it is assumed will
correlate with the odour detected at the boundary or the nearest residential receptor.
For existing facilities, direct measurement of odour using dynamic olfactometry (EN
13725:2003) is recommended for determining odour emission rates. The measurement from
each stack or other sources (basins, tanks, surfaces etc) should be conducted in triplicate, in
order to reduce uncertainty and to enable the identification of outliers. Sampling and analysis
for a specific chemical can only be undertaken adequately where the release is a single
compound although even in this case finding accurate odour detection thresholds can be
problematic. Where more than one compound is present, dynamic olfactometry is the preferred
approach for determining odour emission rates due to the synergistic and non-linear effects of
multiple odorous compounds. Chemical characterization can however be usefully employed to
determine the correct design for an abatement solution as outlined in Section 4.
For proposed installations or the expansion
of existing operations, the modeller should
ensure that the emission rates used are fully
justified in the report. Sources of data may
include libraries of data from similar existing
installations in Ireland (preferably), data
from similar existing installations in other
jurisdictions or, if available, emission factor
databases.
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3.3.1 Relevant Odour Standards
The exposure of the population to a particular odour consists of two factors; the concentration
and the length of time that the population may perceive the odour. By definition, 1 OU
E
/m
3
is
the detection threshold of 50% of a qualified panel of observers working in an odour-free
laboratory using odour-free air as the zero reference.
Currently there is no general statutory odour standard in Ireland relating to industrial
installations. The EPA (EPA, 2001) has issued guidance specific to intensive agriculture which
has outlined the following standards:
Target value for new pig-production units of 1.5 OU
E
/m
3
as a 98
th
%ile of one hour
averaging periods,
Limit value for new pig-production units of 3.0 OU
E
/m
3
as a 98
th
%ile of one hour
averaging periods,
Limit value for existing pig-production units of 6.0 OU
E
/m
3
as a 98
th
%ile of one hour
averaging periods.
Guidance from the UK (EA, 2011), and adapted for Irish EPA use, recommends that odour
standards should vary from 1.5 6.0 OU
E
/m
3
as a 98
th
%ile of one hour averaging periods at the
worst-case sensitive receptor based on the offensiveness of the odour and with adjustments for
local factors such as population density. A summary of the indicative criterion is given below in
Table 3.1 (taken from (EA, 2011) and adapted for Irish EPA use):
Table 3.1 Indicative Odour Standards Based On Offensiveness Of Odour Taken From (EA,
2011) And Adapted For Irish EPA Use
Industrial Sectors
Relative
Offensiveness
of Odour
Indicative Criterion
Note 1
Processes involving decaying animal or fish remains.
Processes involving septic effluent or sludge
Waste sites including landfills, waste transfer
stations and non-green waste composting facilities.
Most Offensive
1.5 OU
E
/m
3
as a
98
th
%ile of hourly
averages
at the worst-case
sensitive receptor
Intensive Livestock Rearing
Fat Frying / Meat Cooking (Food Processing)
Animal Feed
Sugar Beet Processing
Well aerated green waste composting
Most odours from regulated processes fall into this
category i.e. any industrial sector which does not obviously
fall within the “most offensive” or “less offensive”
categories.
Moderately
Offensive
3.0 OU
E
/m
3
as a
98
th
%ile of hourly
averages
at the worst-case
sensitive receptor
Brewery / Grain / Oats Production
Coffee Roasting
Bakery
Confectionery
Less Offensive
6.0 OU
E
/m
3
as a
98
th
%ile of hourly
averages
at the worst-case
sensitive receptor
Note 1 Professional judgement should be applied in the determination of where the worst-case sensitive receptor is located.
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3.3.2 Modelling Procedure
Odour modelling is generally undertaken using either of the two most commonly used air
dispersion models, ADMS or AERMOD, using the same principals as are used when modelling
the release of any other pollutant. Both models have the capability of accepting emission rates
in terms of OU
E
/sec and producing ground level concentrations in terms of OU
E
/m
3
. The same
principals in relation to meteorology, terrain and building downwash will also apply to odour
modelling as per other air emissions as outlined in AG4. When modelling odour, the
measurement of ambient levels of odour and the incorporation of these levels into the modelling
results is not a valid approach as odours are not generally additive due to synergistic and non-
linear effects of multiple odorous compounds in the ambient environment. Secondly, an
ambient odour level from an odour source will typically be masked by existing background odour
level which have been recorded as high as 100 200 OU
E
/m
3
(Yang, 2000) whilst residual
odour in sampling bags can range from 20 50 OU
E
/m
3
(Laor, 2014).
When undertaking the modelling of odour from a facility the following points should be kept in
mind:
The frequency of operation of each source at a facility should be assessed to determine a
suitable time-weighted odour emission rate for each source. Whilst this time-weighted
approach should be the scenario assessed for compliance, it is also appropriate to consider
a scenario with the odour source emitting continuously so that an assessment of short-term
impacts may be considered.
The additional odour releases during transfer and agitation / shredding of materials should
be considered as odour source concentrations may vary considerably on a daily / weekly /
seasonal basis depending on the specific operation / activity being undertaken.
An appropriate odour guideline value should be selected depending on the offensiveness
of the odour. However, good professional judgement should be applied in selecting an
appropriate odour assessment criterion for any particular case and that justification should
be provided for that selection.
For example, if a facility of medium sensitivity has a history of odour complaints it may be
prudent to impose an odour assessment criterion used for high sensitivity facilities.
Likewise, a facility which ducts all emissions through biofilters, thereby changing the
offensiveness (hedonic tone) of the odour, might reasonably have a less stringent odour
impact criterion applied in this case.
Compliance with the indicative odour standard, confirmed through modelling, does not
reduce the licensee’s requirement to ensure that the activity does not cause nuisance.
Odour management at a licenced facility should be proactive, and may require additional
measures to ensure that the activity is in compliance with their licence.
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3.4 Appropriate Abatement Technologies
The elimination, or reduction to acceptable levels, of odour in the Industrial Emissions Directive
(IED) is based on the principle of Best Available Techniques (BAT). However, the IED allows
flexibility in the selection of the appropriate abatement measures to comply with the regulations.
Thus, the selection of the right abatement solution should be based on detailed site-specific
engineering considerations rather than adhering to a specific pre-determined technology.
The CWW BREF Note (EC, 2016) outlines the range of considerations which may need to be
taken into account when selecting the most appropriate abatement solution:
The flow rate of the odorous emissions;
The concentration of the odorous pollutants(s);
The physical and chemical properties of the odorous molecules;
The efficiency of the techniques to abate the targeted odorous pollutants and the
variability over time of this abatement efficiency;
The generation of secondary pollutants;
The energy consumption of the techniques;
The technical limits/restrictions for the use of the techniques (e.g. temperature,
maximum pollutant concentrations, moisture content);
The space requirements of the techniques;
The operation and maintenance requirements of the techniques; and
The cost of the techniques.
A graphical representation of the range of considerations which will need to be considered is
outlined in Figure 3.8.
The odour efficiency of the various abatement solutions varies both between technologies and
between differing processes using the same technologies as shown in Table 3.2 (taken from
(Schenk, 2009)). Where there is uncertainty surrounding abatement efficiency, it is
recommended that a test programme be undertaken on a pilot basis to determine the site-
specific abatement efficiency (as outlined in Section 5). In many cases, there will be sufficient
data sets available to demonstrate abatement efficiency and pilot testing will not be required,
but where such data sets are not available, pilot testing should be undertaken. Detailed
information on the various odour abatement techniques is given in Section 4.
Table 3.2 Odour Abatement Efficiencies And Relative Costs Across Various Techniques
Technique
Odour
Abatement
Efficiency (%)
Examples of
Industry Using
Technique
Note 1
Odour Compound
Removed Most Efficiently
Relative
Cost
Activated Carbon
70 - 99
Waste,
Anaerobic Digestion
VOCs / some H
2
S
Medium
Wet Scrubber
60 - 85
Chemical, Composting
Soluble VOCs / H
2
S / NH
3
Medium
Thermal Oxidation
98 - 99.9
Manufacturing,
Pharmaceutical,
Rendering
VOCs / H
2
S /
Inorganic compounds
High
Bio-filtration
70 - 99
WWTP, Composting,
Anaerobic Digestion,
Rendering, Animal Feed
Soluble VOCs / H
2
S / NH
3
Low
Bio-scrubbing
70 - 80
WWTP
Soluble VOCs / H
2
S / NH
3
Medium
UV / Ozone / Cold-
plasma
< 50 - 98
Food & Drink, WWTP,
Animal Feed
VOCs
Medium
Note 1 The various techniques could apply a greater range of industries than that outlined in this table.
Source: Adapted from Schenk et al. (2009)
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Figure 3.8 Range of Abatement Considerations (based on CWW BREF (EC, 2016)).
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3.5 Methods Of Eliminating Odour (Including Fugitive Odour)
There are a range of methods which may be employed to reduce odour (including fugitive
odour) depending on the specific circumstances of the facility in question:
Box 7- Methods Of Eliminating Odour (Including Fugitive Odour)
At the planning stage of a facility or when undertaking an upgrade, consideration should
be given to locating the more odorous operations furthest from any nearby residential /
sensitive receptors. Consideration should also be given to the prevailing wind and thus
to avoid locating particularly odorous activities immediately upwind of sensitive
receptors.
Truck deliveries of odorous materials should be sealed or enclosed. Truck staging
areas should also be situated away from the nearby receptors. Locating truck staging
areas near buildings will help to provide a wind break.
The facility should operate a “just in time” management approach for odorous material.
Waste disposal should also be undertaken as soon as feasible particularly if there is a
risk of anaerobic conditions occurring. Storage of odorous material should also be
based on “first in, first out” (FIFO) policy.
The OMP should outline a preventative maintenance (PM) schedule for the facility
including preparing relevant standard operating procedures (SOPs) for key odour
control equipment / activities. Maintenance should be proactive rather than reactive.
Mitigation measures for the storage and handling of odorous materials located outdoors
include constructing 3-sided enclosures and relocating activities indoors.
Good housekeeping of all outdoor areas should be implemented particularly during
periods of unfavourable meteorological conditions (for example, decomposition of
organic material will accelerate during warmer periods).
All spills, overflows and leaks should be cleaned up promptly with all operators aware
and trained in the relevant SOP for this procedure.
Chemicals which are potentially odorous or can lead to odorous by-products should be
reviewed as to the potential for product substitution. For example, the use of sulfuric
acid may lead to odorous sulfur-forming chemicals downstream. It may be possible to
replace sulfuric acid with an equally effective alternative.
A local fume hood collection system with flexible hoses may be useful for capturing and
extracting fugitive odours from sources with odour potential. Localised containment will
reduce the volume of air to be extracted and, if necessary, treated.
For the transfer or delivery of odorous liquids, vapour recovery or a closed-loop system
should be used.
Extraction of air through a negative pressure system to a point source will reduce
fugitive emissions associated with passive sources such as general ventilation
exhausts, louvers, windows or doors.
A building integrity test is recommended for any building where odorous material is
stored. Ideally, the building should have a negative pressure system installed with the
extracted air ducted to a vertically pointed stack (and possibly with an abatement
system prior to release where the need arises). Self-closing doors and trigger alarms
on roller doors should also be installed.
A waste storage plan should be developed.
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3.6 Minimisation Of Odours That Cannot Be Abated
Odours which cannot be abated can be minimised by implementing the following practices:
Box 8 - Minimisation Of Odours That Cannot Be Abated
In certain instances, odour can be effectively minimised by process design and
operation. Odorous emissions from intensive agriculture can be minimised through
animal nutrition for example (reduction of protein in feed).
The facility should have a high level of cleanliness with outdoor surfaces washed down
regularly with any remaining stagnant water removed. Cleaning of waste and storage
bins, trucks carrying odorous materials and holding vessels should be undertaken
regularly with an increased frequency in summer months.
A closed-door policy should be strictly enforced where there is the potential for
odorous releases through open doors.
Keeping the temperature as low as possible will reduce evaporation and thus odorous
material should be kept out of direct sunlight and refrigerated if possible.
Increasing the humidity and reducing airflow over the surface of the odorous liquid will
reduce the rate of evaporation (the rate of evaporation is directly proportional to the
speed of air flow over the liquid surface).
Reducing the exposed surface area of liquid storage tanks by using floating covers
will reduce the rate of evaporation and subsequent release to atmosphere.
Activities such as agitation, shredding and mixing (turbulence) in liquids and solids will
increase the odour emission rate significantly. These activities should be undertaken
with appropriate mitigation measures in place.
Adjustment to pH can increase the solubility of certain odorous compounds in water.
For example, acidic conditions will suppress the evaporation of ammonia and similar
alkaline compounds. Likewise, increasing alkalinity will help suppress H
2
S release to
atmosphere.
Odour neutralisers may be useful in certain limited circumstances where intermittent
odours occur although these are generally not a long-term solution.
The addition of surfactants to aqueous solutions will help to shift the air-water
equilibrium of volatile organic compounds leading to decreased rates of evaporation.
Stack design to ensure that extracted air is dispersed adequately is important. The
exhausted air should have sufficient stack exit velocity and an appropriate stack
diameter to avoid stack-tip downwash (typically greater than 10 - 15 m/s required).
The stack height should be sufficient to avoid significant building downwash and be
directed in a vertical direction without rain caps on top of the stacks.
Fugitive emissions such as valves, pump seals, flanges and leaks should be
investigated using appropriate methods (for example photoionisation detection (PID))
and followed up with a corrective action programme.
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3.7 Odour Complaint & Investigation Procedure
The OMP should formalise the procedures for dealing with any odour complaints. A
recommended odour complaint procedure is outlined below in Box 9 with a template for the
Odour Complaint Report Form shown in Appendix A. A detailed odour wheel in Figure 3.9
shows the characteristic odours associated with major odorous sources.
Box 9 - Odour Complaint Procedure
The facility is required to have a notice board with contact details as part of the
Licence. These contact details should be used for logging odour complaints with
experienced personnel available to answer calls during normal working hours.
A phone number should be available outside of normal working hours with a follow-
up call made as soon as possible to the caller by an appointed person.
The staff personnel taking the call should request the information as outlined in
Appendix A of this guidance including details on:
Time, date and where the odour was detected,
Duration of the odour,
How strong is the odour?
Describe the odour (suggested odour types are outlined in Figure 3.9).
The staff personnel should record any other relevant aspects of the call including the
responses made to the complainant.
The staff personnel should immediately arrange for a company representative to
undertake an odour impact assessment in line with AG5. The survey should
commence upwind from the facility with a visit to the location of the detected odour
also undertaken to verify the nature of the odour.
If the nature of the odour can be linked to the facility, the company should undertake
a site audit to identify the source of the odour.
Once identified, the odour source should be investigated to determine whether there
has been an operational failure or a failure of an abatement system with steps
implemented to rectify the problem.
In the event that the odour source cannot be serviced / rectified immediately, it may
be necessary to cease operations until the issue is resolved.
Where no odour is detected by the company representative at the location of the
complainant, the complaint should not be dismissed out of hand. Odour detection can
be transitory whilst the company representative may have a higher odour threshold
compared to the complainant.
A site audit should be undertaken in any case to confirm or otherwise the source of
odour release. Once the odour investigation is completed, the company should follow-
up to brief the complainant as to the outcome of the investigation.
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Figure 3.9 Characteristic Odour Wheel Based On Major Odour Sources
Adapted from the odour wheel described in (Suffet, 2009)
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3.8 Odour Management Plan Template
The odour management plan should be based on a standardised and consistent methodology.
A suitable template for undertaking a OMP is outlined below with a detailed checklist outlined
in Appendix B. In order to be effective, the OMP should be fully integrated into the site EMS
and adjusted as circumstances change onsite.
Introduction This should outline the purpose of the odour management plan and include a
policy commitment from the company signed by senior management / directors.
Facility Details This section should cover the setting of the facility in the local environment
with details on nearby sensitive receptors. A figure of the facility showing the receptors should
be provided with a windrose included to identity the prevailing wind direction.
Legal Framework - The licencing regime under which the facility operates should be delineated
in addition to any relevant odour conditions which are specified in the licence. The type of
processes and activities undertaken at the facility should also be discussed in this section with
a clear description of how the process could give rise to odour pollution. The OMP should also
demonstrate that the licensee has the competence and knowledge to manage that risk
effectively.
Structure / Designation of
Responsibility The
management structure of the
organisation should be outlined
from Senior Management,
through General Manager and
Environmental Manager down
to the relevant operators of the
process control equipment
detailing responsibilities of the
key personnel. Responsibilities
for each control measure and
each aspect of routine
maintenance should be
highlighted in detail for each
task with back-up personnel
nominated in case of absence
of the duty personnel.
Critical Paths of Potential Odour Sources The OMP should identify the potentially odorous
activities and materials used onsite. A process flow diagram of the operations onsite (such as
Figure 3.4 and Figure 3.5) will help to identify high risk sources for odour release, such as
transfer points, high temperature processes, material open to atmosphere, loading / unloading
etc. Any odorous release points should be documented by way of a detailed odour audit of the
facility.
The critical paths for relevant release points should be identified on a map to aid the
interpretation of the cause of the odour complaint (Source-Pathway-Receptor concept). The
potential release route(s) should be considered under normal and abnormal operations.
Routine Methods / Control Measures The routine methods and control measures which are
implemented onsite to minimise odour should be described in detail. This should cover
measures which are undertaken under normal operation such as:
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deliveries of materials / inventory,
inspection and storage of materials,
correct use of plant and processes,
checks on plant performance,
planned maintenance and repair
schedule,
containment measures,
treatment of odorous materials,
abatement of odorous emissions and
export offsite of materials.
The frequency and scheduling of each action should be recorded with the person responsible
for undertaking the action identified. The planned inspection, maintenance and repair schedule
for odour critical equipment should be outlined with responsibility assigned to relevant
personnel.
Monitoring The plan should identify a series of planned onsite checks, inspections and
measurements to ensure that all process parameters (such as pH, oxygen level, pressure,
temperature, moisture level) are within design parameters on either a daily, weekly or other
defined frequency as required. This may change on a seasonal basis due to meteorological
conditions or increases in capacity at certain times of the year.
Where parameters are outside of the design range, the measures which will be employed to
address the non-compliance should be addressed and itemised. For example, if the pH level
in a settlement tank is too low, the solution to the problem (dosing with sodium hypochlorite for
example) should be written into the plan. Also, where stack monitoring determines that the
odour emission rate is greater than the abatement system design level the abatement system
should be scheduled for servicing / repair.
Odour impact assessments (possibly daily depending on the risk factors) should also be
formalised in the OMP with a log of who is responsible for undertaking the survey, the time of
day, meteorological conditions and the results recorded in line with AG5 (EPA, 2019).
Emergency / Abnormal Operation The facility should undertake an odour risk analysis to
determine the risk of a failure of an odour control measure or abatement system. The review
should identify the likelihood, severity and consequences of each scenario / risk. The review
should also include an assessment of the odour impact area of the relevant odour sources.
Risk factors for abnormal operation should be identified such as ambient conditions (high
temperature, low rainfall, calm weather), onsite equipment failures (abatement system
malfunction, power failure, loss of negative pressure etc) and human error (spillages, doors left
open, uncovered trucks). The risk factors should be itemised with the likely consequences of
each scenario documented. Abatement equipment spare parts which are essential for the
operation of the facility should be purchased and stored onsite to minimise downtime to the
abatement system and possibly production downtime.
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Corrective Measures For each
item identified in the risk analysis,
there should be a discussion as to
the additional measures, and an
action plan, which will be employed
to address and minimise the likely
consequences.
For example, during periods of high
ambient temperature, the
acceptance of waste at a transfer
station may need to be reduced with
any additional waste diverted to
lower sensitivity locations.
Similarly, when abatement systems
fail it may be necessary to cease or
significantly reduce operations until
the problem is rectified.
Community Liaison The OMP should formalise the procedures for liaising with the local
community. This should focus on building a positive relationship with the neighbouring
community, include mechanisms for communicating with those individuals / local resident
groups / organisations seeking information on the odour control measures employed at the
facility, the frequency of complaints and improvements / changes onsite. A log of all
communications should be kept as part of the OMP file.
Review Process The OMP is a dynamic document which will require reviewing and possibly
updating on an annual basis, as a minimum. Where a facility is subject to odour complaints,
the OMP may need to be reviewed more frequently with the corrective action required to deal
with the complaints incorporated into the OMP. The OMP will also need to be updated to take
account of changes to operations, infrastructure or due to changes to the efficiency of the
mitigation measures.
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4.0 SUMMARY OF ABATEMENT TECHNOLOGIES
Odour abatement technology must achieve the destruction, transformation or removal of
odorous compounds from an exhaust stream, prior to this exhaust being discharged to the
outside environment. Correctly selecting the abatement technique which best destroys,
transforms or removes the odorous compounds in the most efficient manner is key to successful
odour control.
An understanding of odour chemistry is critical to the selection of the most appropriate odour
abatement technology. Many odour abatement projects have failed to deliver the required
odour destruction efficiency due to a failure to understand the chemistry of the odour molecules
causing the odour impact.
Odour abatement technologies need to be selected by following a systematic approach
technologies can often be selected based on incorrect assumptions, a lack of appreciation of
odour chemistry or a failure to understand variations in loading rates, therefore a systematic
approach will be presented in this guidance. This approach begins with the characterisation of
the odorous compounds, which can be achieved by a combination of olfactory techniques
(smelling the odour and deciding that it smells like rotten eggs for example, which indicates the
presence of hydrogen sulfide or mercaptans) and chemical analysis, which can be used to
determine whether the odorous compounds are mercaptans or hydrogen sulfide.
A process design approach should be applied to the selection process. Design is the
development of a plan to accomplish a goal. In this case the goal might be to meet an emission
limit value at a stack emission point or to achieve no offsite odour. Defining that goal and stating
it at the start of the process will ensure the best project outcome.
The definition of the inputs to the abatement technology is critical, data should be collected to
define the following:
Composition of the exhaust stream (chemical composition, water vapour, dust
concentration, odour unit concentration),
Flow rate,
Hours of operation,
Air stream temperature and pressure,
Variation in operating parameters.
The primary reliance to define each of the above must be on competent practitioners using
independently certified equipment, to ensure the best possible foundation for the selection of
the equipment. It is often found that abatement equipment fails to perform due to assumptions
made on input parameters, whereas measurement may have defined different values for input
parameters.
The environmental footprint of odour abatement technology is also an important consideration
many odour abatement technologies consume significant energy, produce wastewater,
wastes or by-products or consume significant quantities of chemicals which in turn have
associated environmental risks. The environmental footprint should therefore be factored into
odour abatement technology selection.
It is important that a systematic approach is also adopted to abatement technology specification
often incorrect specification of odour abatement technology occurs which in turn leads to a
failure of the installed unit to achieve the required odour removal rates. This guidance sets out,
in the following paragraphs, a standard approach to specification that includes the range and
nature of odours, air flows, temperatures and pressures, to enable a standardised and
sufficiently robust approach to specification.
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When considering an odour abatement requirement, three important factors should be
considered:
What compounds are likely to be causing the odour?
What are the options for removing them from the air stream? Can the compounds be
removed by absorption, adsorption or scrubbing, or can the compounds be in some way
denatured or removed using oxidation or other chemical reactions?
When the technologies that are shortlisted for abatement are considered, which has the
lowest capital, operational and environmental cost (where environmental cost focuses on
the environmental impact of the technology, both direct impacts such as the combustion
of fuel onsite, the generation of wastewater or spent filter media, and indirect impacts
such as electricity consumption).
The following matrix in Table 4.1 is a useful guidance tool for determining which odour
abatement technology may be appropriate for a given situation:
Table 4.1 Matrix of Odour Abatement Technologies
System
Appropriate For
Not Appropriate For
Pros / Cons
Activated
Carbon
Removal of all organic
odorous compounds.
Dust
Requires pre-treatment dust removal
system, operating costs are high due
to regular requirements for filter and
carbon change out. Dust removal can
be achieved but dust will block the
carbon filter and therefore pre-
treatment is required.
Thermal
Oxidation
Removal of all odorous
compounds.
Dust
Requires pre-treatment dust removal
system, high capital and operating
cost, risk of dust explosion or fire if
dust abatement system fails.
Biofilter
Removal of all odour
compounds, efficiencies
greater than 90%
reported.
Dust
Needs dust pre-treatment system,
which requires bag filter or similar, dust
removal can be achieved but dust will
block the biofilter and therefore pre-
treatment is required.
Bio-scrubber
Removal of dust and will
reduce odorous
compounds (including
less soluble compounds)
by at least 50% (likely
range 50-60%).
Some residual odour
No pre-treatment system needed, but
system does produce effluent to sewer.
UV / Ozone /
Cold-plasma
Removal of Organic
compounds.
Ammonia, H
2
S, dust
Only removes some compounds,
requires pre-treatment to remove dust.
Wet Scrubber
And Biofilter
Combination
Removal of dust and will
reduce odorous
compounds by at least
90%.
Very low residual
odour
Achieves much higher odour removal
rate but costs and complexity are
greater.
There are three key headings to consider when deciding on the selection of odour abatement
equipment which are outlined in Box 10:
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Box 10 - Engineering, Environmental and Economic Considerations
Engineering
Chemical and physical characteristics of the emissions,
Dust or particulate loading,
Design and performance characteristics of the proposed abatement unit,
Contaminant destruction or removal ability,
Reliability,
Dependability,
Ability to consistently meet targets,
Turn-down capability, and
Ability to deal with fluctuations, temperature limitations, maintenance requirements.
Environmental
Equipment location,
Available space,
Ambient conditions,
Availability of utilities and waste disposal systems,
Emission limits,
Visual impact (e.g. steam or vapour plume),
Impact on wastewater infrastructure,
Impact on local noise environment.
Economic
Capital Cost:
equipment,
installation,
civils,
structural,
engineering design.
Operating cost:
utilities,
chemicals,
maintenance.
Equipment lifetime.
4.1 Appropriate Abatement Technologies
Of fundamental importance to selecting an odour abatement solution is that one must
understand the fundamental mechanism at work at the heart of the abatement technology and
the chemistry of the molecules causing the odour. This allows one to select the abatement
process which is most suitable to the characteristics of the molecules requiring removal or
destruction.
4.1.1 Activated Carbon
Activated carbon technology is based on the physical adsorption of odorous compounds on an
activated carbon bed by intermolecular forces of adsorption (it is important to clarify an often-
repeated error Adsorption is the removal of molecules from a gas stream by attachment to
a solid, Absorption is the removal of molecules from a gas stream by transfer into a liquid
medium). The key processes involved in this technique are outlined below:
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The molecules being removed from the air stream are known as the adsorbate, the
solid doing the adsorbing is known as the adsorbent. The attractive forces that hold
the molecules to the surface of the solid are the same that cause vapours to condense
(van der Waals forces).
All gas / solid interfaces exhibit this type of attraction, some more than others, so all
adsorption systems use materials to which the molecules to be removed are strongly
attracted.
The molecules removed are merely stored on the surface of the adsorbent, and over
time the adsorbent becomes saturated with the adsorbate and must be disposed of or
regenerated.
Adsorption can also occur by a chemical process, where the target molecules react
with the adsorbent, forming a chemical bond by exchange of electrons. This process is
not easily reversible and is less commonly used in odour abatement. An example
where it may be of use in odour abatement is the use of iron oxide chips to remove
hydrogen sulfide from an exhaust stream.
In an adsorption process such as activated carbon where the adsorbed odorants are
stable and poorly reactive, they will remain trapped in the solid adsorbent. If the
odorants are reactive, they may chemically react with other compounds adsorbed.
For instance, reduced sulfur compounds are oxidized in the presence of atmospheric
oxygen when adsorbed in activated carbon.
Adsorption processes usually take place in packed carbon beds in cylindrical tower
units at gas residence times ranging from 1.5 10 secs.
At the end of the carbon packing lifespan or when no regeneration of the activated
carbon is possible, one of the towers will be in operation while the packing material of
its counterpart is substituted.
Activated carbons are usually obtained by activation at high temperature of organic
materials such as wood or coconut fibre (coir). This process is not part of the
abatement system onsite, instead it is conducted at an offsite location which could be
owned and operated by the activated carbon supplier.
It should be noted that in many cases the activated carbon supplier does not offer a
regeneration service, in which case the activated carbon must be disposed of as a
waste material.
Activation involves firstly heating the substrate (such as wood, coconut fibre) to 600
o
C
to drive off all volatile material, essentially leaving only carbon behind. This material is
then exposed to air, steam or carbon dioxide at higher temperatures. This process
attacks the carbon surface and increases the pore numbers and surface area of the
carbon.
Manufacturers vary the process
temperatures, times and
substances to produce carbons
which are more suitable for different
applications. This is important to
note for the selection of activated
carbon systems for odour control.
It should be made clear to the
supplier of the carbon what the
target compounds and application
is, so that the most appropriate
grade of carbon can be provided.
Adsorption does not require the
transfer of odorants to an aqueous
phase, and the high affinity of the
adsorbent for hydrophobic
compounds (compounds which are
poorly water soluble) supports the
highest abatement efficiencies for
these odorants (up to 99.9%).
However, the removal efficiencies
for hydrophilic VOCs are lower,
generally ranging from 80 to 90%.
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Overall, activated carbon adsorption typically has higher removal efficiencies compared to
biofiltration and chemical (wet) scrubbing. The adsorption capacity of a carbon bed depends on
a number of factors such as:
the nature of the material,
the odorant concentration in the gaseous stream,
the operation temperature and humidity, and
the mixture of odorants present in the emission.
In some specific scenarios, a high humidity in the malodorous stream or its uctuations can
hinder the design and operation of adsorption systems. For example, water molecules compete
with odorant compounds for the active sites of the carbon.
Activated carbon has a strongly non-polar surface and therefore will attract solvents, other
VOCs, organic odour compounds and some toxic gases. A typical capacity value of 0.1 g
adsorbed compounds/g activated carbon is often considered for design purposes. The bulk
density of an activated carbon bed varies from 0.3 to 0.5 g/cm
3
depending on the grade of
carbon being used. Typically activated carbon used for odour control will have an internal
porosity in the range of 55 to 70% of carbon volume and a surface area of a quite extraordinary
600 to 1600 m
2
/gram.
Mean pore diameter is in the range of 150 to 200 nanometres (nm) with most gaseous air
pollutant molecules in the range of 40 - 90 nm. Carbon with pore diameters of less than 40 nm
will not be effective in air pollutant removal, hence the need to carefully select the carbon grade
required.
Activated carbon adsorption presents a low environmental impact when the sustainability
analysis is only performed on the odour removal process. It is a low resource usage method
when applied at relatively low odorous compound concentrations. In addition, the low residence
times applied in this technique reduce the land needs, supporting high removal rates in compact
systems.
In terms of investment costs, adsorption systems also benefit from the small required gas
contact time and the wide application and accumulated experience.
The robustness of activated carbon filtration ranks this technology as the most practicable odour
abatement method applied nowadays. The relative simplicity of the technology (no water or
chemicals needed, and no process control involved) implies that common issues in odour
abatement scenarios such asuctuations of inlet odorant concentrations, foul air interruptions
or air temperature fluctuations will result in minor or marginal effects on the odour abatement
efficiency. However, it must be noted that duplicate or backup systems are often needed to
guarantee a consistent odour removal during packing material replacement or regeneration.
The high odour removal efficiencies supported by activated carbon adsorption systems provide
the highest benefits to the nearby population and to the health and welfare of employees.
Activated carbon units are less suitable for dusty conditions often found in the waste industry,
where air is extracted from waste handling and storage sheds, without the use of a pre-filtration
system to remove dust. This leads to the requirement for a unit fitted with cartridge filters which
remove dust from the air stream, which adds to cost and maintenance requirements. Monitoring
of the pressure drop across a carbon bed and across the ducting feeding the carbon bed should
be undertaken to check if the ducting or bed is starting to block from an accumulation of dust.
Differential pressure across the carbon bed should be checked on a regular basis to ensure it
remains within the range specified by the equipment supplier.
An important consideration as noted above is also to avoid moisture entering the carbon system
as this reduces the efficiency of the carbon considerably. Where warm moist air is being fed to
a carbon system (such as from composting) the incoming air should be cooled to condense the
water vapour (this has the added advantage of removing water soluble compounds which
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reduces odour loading). It is also important to ensure that the carbon bed can be accessed via
a manway access cover at the base of the unit, so that in the event of a requirement to replace
the carbon bed, the manway can be used to access the bed and enable the bed to be dug out,
it is much more difficult to dig out a carbon bed by accessing from the top of the vessel.
A carbon bed can become saturated by the compounds removed from the air stream being
treated, leading to an event known as breakthrough, where the carbon bed becomes saturated,
(meaning there are no sites remaining to achieve adsorption). To ensure the carbon bed is
replaced before saturation occurs, reference should be made to the manufacturers calculations
for intervals between bed change out, and periodic monitoring for indicator species should be
conducted using on-site monitoring equipment.
As discussed in the general description of adsorption, activated carbons can exhibit a wide
range of H
2
S capacities, depending upon the type of carbon used. An industry standard test,
ASTM D-6646, was adopted many years ago to provide a common measuring stick for activated
carbon H
2
S capacities. This test yields a H
2
S capacity measured in grams of H
2
S removed per
cubic centimetre of carbon utilized. The following table allows for a simple comparison of the
carbons discussed:
Carbon Type H
2
S Capacity
Standard Carbon 0.01 0.03 g/cc
Impregnated Carbon 0.12 0.14 g/cc
Blended Carbon 0.14 0.27 g/cc
Catalytic Carbon 0.09 0.63 g/cc
What this means for designers is that
standard carbon should only be used to
treat low levels (1 to 2 ppm) of H
2
S, while
impregnated, blended, and catalytic
carbon can be economically used to treat
H
2
S levels as high as 20 to 30 ppm.
Image courtesy of ERG (Air Pollution Control) Ltd.
www.ergapc.co.uk
4.1.1.1 Organic Sulfur Compounds
This class of compounds is the most prevalent in waste odour control after hydrogen sulfide.
Typical compounds include methyl mercaptan, dimethyl disulfide, and carbonyl sulfide. In all
cases, these compounds will be removed by activated carbon via physical adsorption.
Caustically impregnated carbons and blended medias do not provide added capacity for these
compounds and in fact, the presence of the metal oxides in or on the carbon decreases the
physical adsorptive capacity of the carbons. As these compounds are removed via physical
adsorption, there is no way to regenerate the carbon in situ. Carbon can economically treat
organic sulfur compounds up to the low ppm (1 - 5 ppm) concentration level. Higher
concentrations than these will typically exhaust the carbon so frequently that carbon exchanges
will represent an unreasonable expense and operator headache.
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4.1.1.2 Amines
Activated carbon can provide useful capacity for most amine compounds found in municipal
wastewater. However, as with the organic sulfur compounds, carbon has a finite capacity for
such compounds and cannot be regenerated in situ and so tends to be quickly exhausted.
4.1.1.3 Ammonia
Most activated carbons are ineffective for ammonia removal. The ammonia molecule adsorbs
very poorly on carbon and breakthrough occurs rapidly. Carbon is not typically recommended
for ammonia removal. One exception involves the use of acid-impregnated carbon. However,
this is usually not as cost effective as other means of ammonia reduction.
The positives and negatives of activated carbon are shown in Box 11:
Box 11 Positives & Negatives of Activated Carbon
Pro’s
Widely used well established technology,
Can achieve high removal efficiencies (90 98%),
Suitable for a wide range of gas flow rates (100 to 100,000 Nm
3
/hour),
Able to handle a wide range of VOC loading rates (from 20 to 5,000 ppm),
Suitable for varying flow rates and loading rates provided the unit is sized to deal
with variable loadings.
Con’s
Carbon bed fires are a risk the adsorption of high concentrations of some
compounds such as mercaptans onto the carbon bed can lead to localised
hotspots (due to the heat released by the adsorption process) which can ignite
flammable gases or dust,
Bed performance declines with time due to carbon attrition where small quantities
of VOCs gradually bond to the carbon and block the active sites,
Efficiency of removal decreases significantly above 50% relative humidity (RH)
meaning that moisture laden odours from facilities such as composting plant will
be difficult to treat in an activated carbon system,
Dust blockages are a risk as noted above mean pore size on the carbon is in the
range of 100 200 nm (0.1 to 0.2 m), with most dust particles being orders of
magnitude greater than 0.1 to 0.2 m. Therefore, for dusty applications, such as
waste transfer stations, pre-filtration will be required in the form of cartridge filter
systems which are expensive and require frequent replacement (for some sites
replacement is required every 2-3 weeks),
Not considered cost effective above 5,000 Nm
3
/hour, at which point wet scrubbing
/ bioscrubbing (or biofilter if the space is available) is considered more cost
effective.
Channelling within the carbon bed (where channels are formed over time through
which exhaust air can flow, with minimal contact with the carbon) is an issue which
can lead to a decrease in odour removal efficiency. Monitoring of pressure drop
across the carbon bed, which will show a reduction in pressure drop if channelling
occurs, is an effective method for detecting channelling.
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4.1.2 Thermal Oxidiser
Thermal oxidation of the air exhaust is undertaken at temperatures between 800 and 1100
o
C.
At these temperatures, hydrocarbon compounds are oxidised to produce carbon dioxide, water
vapour and compounds such as sulfur dioxide (if sulfate is present) and HCl (if chlorine or
chlorides are present). Thermal oxidation systems are relatively simple pieces of equipment
capable of achieving very high removal efficiencies of target compounds. However, it would be
very unusual to select thermal oxidation for odour removal as a majority of odorous air streams
in industry (food industry, waste industry, wastewater plants) are at ambient or room
temperatures.
A Regenerative Thermal Oxidiser (RTO) may reduce fuel usage significantly depending on the
air temperature and components of the air stream, but these operating costs are simply
uneconomical for the abatement of most odorous air streams.
It should be noted that incomplete combustion of organic compounds which can occur could
lead to the formation of aldehydes or organic acids, which can create air pollution issues, or
combustion of halogens can lead to the creation of hazardous substances such as sulfur
dioxide, hydrochloric acid, free chlorine, phosgene or hydrofluoric acid, which require further
treatment systems for their removal and which create waste streams requiring disposal.
Thermal oxidisers can be either:
4.1.2.1 Direct Fired (DF)
A direct fired oxidiser is the most energy inefficient type of thermal oxidation, as it does not
allow for heat recovery in a standard direct fired oxidiser configuration, as shown in Figure 4.1.
Figure 4.1 Direct Fired Oxidiser
This type of abatement is not normally used for odour abatement. It is usually only applied
where the incoming air has a component such as fluoride, which would be oxidised to produce
HF (hydrogen fluoride gas) which is extremely corrosive and attacks the majority of metals and
ceramic media used in RTO units (see below). For this reason, direct fired oxidisers are brick
lined to prevent corrosive gases corroding the metal from which the unit is manufactured.
Therefore, it would not be expected that DF (direct fired) oxidisers would be used for odour
abatement. In addition, it should be noted that DF oxidisers are highly energy inefficient, with
each m
3
of incoming air being heated from ambient temperature (circa 10 - 20
o
C) to 850 -
1100
o
C with this energy being discharged to the environment as waste heat. DF oxidisers can
be fitted with heat recovery systems in the form of a heat exchanger on the exhaust system.
However, most applications lead to the formation of corrosive gases by the combustion process.
Thus, the heat exchanger must use very expensive metals such as Hastelloy (a nickel-based
steel alloy), and even then corrosion may occur, making heat recovery not an option for most
applications.
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4.1.2.2 Recuperative Thermal Oxidiser
A recuperative thermal oxidiser is similar to a direct fired unit except that a heat exchanger is
installed downstream of the oxidation unit as shown in Figure 4.2. This allows for partial energy
recovery with the recovered energy being available to heat incoming air or to be used as a
process heat supply.
Figure 4.2 Recuperative Thermal Oxidiser
This kind of energy recovery is only suitable for gas streams that do not contain precursors of
corrosive substances. If corrosive substances are formed as a result of oxidation of the exhaust
gas, corrosion problems are likely to occur in the heat exchanger, making this kind of technology
unsuitable for such gases. Recuperative Thermal Oxidisers are rarely used as the RTO unit
(described below) is considered much more energy efficient.
Both direct fired and recuperative thermal oxidisers are generally not considered appropriate
for abatement of odorous compounds due to high capital and operational costs.
4.1.2.3 RTO (Regenerative Thermal Oxidiser)
The RTO is the most energy efficient form of thermal oxidation and may in some cases be
considered appropriate odour abatement technology where odorous compounds are not
susceptible to treatment by other abatement options. These systems contain a ceramic
honeycomb media where the oxidation process takes place. A burner fuelled by natural gas,
oil or an electrical heat source raises the incoming air temperature to the required temperature
with the ceramic honeycomb medium ensuring that this heat is recovered and used to minimise
the amount of fuel or energy required.
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Figure 4.3 Schematic of how RTO operates
Images provided courtesy of Brofind SPA
An example of a RTO unit is shown in Figure 4.4 below.
Figure 4.4 An Example Of An Operating RTO Unit
Image courtesy of Dürr Systems AG
As shown in Figure 4.3, incoming air (the red exhaust stream) enters the first oxidation chamber
where it is oxidised. The valve arrangement for the unit then vents this cleaned air to the second
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chamber, where the heat from this air is absorbed by the ceramic media, resulting in the exhaust
gas exiting the oxidiser at a temperature in the region of 110 - 130
o
C.
The next portion of incoming exhaust air is then directed by the valving arrangement to the
second chamber which is now at its operational temperature of 850
o
C, and oxidation occurs in
this chamber. The hot gas from this chamber then exits and is directed to the 3
rd
chamber
where it raises the chamber temperature to the operational temperature required, and the
incoming gas is diverted to this chamber. In this manner the RTO continues to cycle efficiently,
achieving destruction of odorous compounds while minimising energy usage. RTO units can
achieve up to 97% energy efficiency.
Thermal oxidation units are best suited to odour abatement where the odorous compounds are
solvent fumes, paint fumes or other such VOC derived odours, which are present in relatively
high concentrations and which oxidise exothermically to generate heat which contributes to the
temperature of the oxidiser unit.
The positives and negatives of thermal oxidation are shown in Box 12:
Box 12 Positives & Negatives of Regenerative Thermal Oxidation
Pro’s
RTO is a highly energy efficient technology,
Stable robust technology,
Once the unit is at operational temperature there is minimal risk of emissions short-
circuiting or channelling or failing to be abated,
Destruction efficiencies of >99.9% are readily achievable,
Energy contained in incoming compounds is used in the process to provide
thermal input.
Con’s
Capital and operational costs are relatively high,
These units are poor at coping with variable flow rates and loading rates,
Corrosive gases are formed if compounds such as sulfur, fluorine or chlorine are
present in the incoming gas stream,
Not cost effective at low incoming gas concentrations with low VOC load,
Valve seat (the valve seat is the component against which the valve closes to
ensure a seal) wear and subsequent leakage across the valve units into the
exhaust stream leading to emission limit breaches,
Burner issues can be experienced where condensation forms on burner units,
stopping the unit from firing after being off-line for a period. This needs to be
mitigated by either trace heating the burner unit or thermally isolating it from the
external environment.
4.1.2.4 Management and Monitoring of Thermal Oxidation Systems
Thermal oxidation systems require relatively low operator input although the combustion
chamber operating temperature should be clearly displayed at all times for viewing by the
operator and should also be recorded. The operating temperature within the unit is monitored
by at least two thermocouple units within the oxidiser bed combustion zone, which in turn signal
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to the PLC controlling the unit to adjust fuel flow to maintain operating temperature. Operating
pressure is also monitored within the oxidiser bed to ensure that any pressure rise due to
blockages is detected before it becomes an issue.
Operator input is usually limited to periodic checks on operating temperature (which is also
alarmed). Consequently, in the event of a drop in operating temperature, operators are alerted.
More sophisticated monitoring is available in the form of on-line CEMS (Continuous Emissions
Monitoring Systems) which provides real-time data on combustion products and enables more
sophisticated control of the oxidation systems.
Reference oxygen concentration should be established for a thermal oxidiser. It should be
noted that in most cases the reference oxygen will be very close to that of ambient air, unlike a
boiler where the majority of the air used is consumed in the combustion process, leading to a
low oxygen content exhaust. A thermal oxidiser raises air to the required operating temperature
to enable the oxidation of target compounds with very little of the exhaust oxygen consumed in
the process.
4.1.3 Biofilter
A biofilter consists of a bed of soil, sea-shells, wood chips, heather or compost, underneath of
which is a network of perforated pipework.
Odorous air is blown through the pipework and up into the bed where micro-organisms remove
odorous compounds. Crucial to the operation of a biofilter is a stable environment where micro-
organisms will thrive. The organic substrate provides salts and trace elements for the bacteria
and volatile organic compounds within the air provide the food source for the bacteria. The key
component parts of a biofilter are shown below in Figure 4.5. It will be seen that the design is
relatively simple, meaning construction costs are relatively low but land requirements are
relatively larger than technologies such as scrubbing.
Figure 4.5 Biofilter Technology Design
Biofiltration is a well-established technology, with 30 40 years of operational history. It is
effective at dealing with VOC loading rates up to 1000 ppm (as C) and offers a low cost, low
maintenance solution although as noted above there is a significant land take associated with
biofilters. Reported odorous compound removal rates are in the region of 95 - 99% with removal
rate variables being media type, operating temperature, bed pH and residence time.
Odorous organic compounds are metabolised by bacteria in the bed into carbon dioxide and
water and other oxidised compounds such as sulfur dioxide. Hydrogen sulfide, ketones, thiols,
amines, esters and organic acids are all readily degradable in biofilters. Generally, incoming
air to a biofilter may need to be humidified with water to saturate the air stream, which enhances
biodegradation of odorous substances.
Biofilters range in depth from 0.5m to 2.5m, depending on required residence time and media
type, with most biofilters being about 1m deep. A number of media types (listed above) all have
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common characteristics required for a biofilter which are, a neutral pH, pore volumes of 80% or
greater and organic carbon content of 55% or greater.
The micro-organism population in a biofilter can be divided into 3 broad categories, fungi,
bacteria and actinomycetes (which are organisms that resemble both bacteria and fungi). For
optimum performance the micro-organisms require an aerobic environment, adequate moisture
(damp but not saturated), neutral pH and ambient temperatures. The start-up of a biofilter
typically requires about two weeks for the micro-organisms to become accustomed to the
specific compounds in the exhaust stream.
Biofilters can be suitable for applications where odours may be generated on a campaign basis,
whereby a composting or other such process may only discharge air at intermittent periods,
and indeed biofilters can be maintained in a standby arrangement for up to 2 months once
moisture, nutrient and air supplies are maintained.
Typically, a Carbon/Nitrogen/Phosphorous ratio of 100:5:1 in the media is required to provide
adequate conditions for micro-organism growth. Water content of the media should be in the
range of 20-60% by weight. pH should remain in the range of 7-8, biofilters with high hydrogen
sulfide loading can experience reduced pH as hydrogen sulfide converts to sulfuric acid. This
needs to be adjusted by the addition of lime or the use of a higher pH medium such as sea-
shells.
Biofilters are sized based on retention time (a minimum retention time of 30 seconds is required)
and on loading rate, within the range of 0.3 -1.6 m
3
/min-m
2
. For a small to medium sized waste
transfer station, which would typically generate in the region of 10,000 Nm
3
/hr of exhaust air
from waste storage buildings, assuming a median loading rate of 1 m
3
/min-m
2
this would equate
to a 166 m
2
biofilter. This would be in the region of 18m x 9 m (length by width) and not every
site will have this space availability, considering that additional area will be required for fans,
humidification unit and control panel.
The positives and negatives of biofilters are shown in Box 13:
Box 13 Positives & Negatives of Biofilters
Pro’s
Relatively low cost, low technology units.
Ability to treat large gas volumes with dilute concentrations of odorous compounds,
Allow the biotransformation of pollutants (i.e. they are broken down into other non-
odorous compounds).
Con’s
Not suitable for high concentration odour streams,
Requires regular checking and monitoring to ensure bed pH and moisture content
remains within required limits,
Large land-take required relative to other technologies,
Performance decreases in cold weather due to effect of ambient temperature on
bacterial kinetics. The rate of bacterial reaction doubles for every 10
°
C rise in
temperature but the opposite is also true for a fall in temperature.
Sensitive to shock loading in cases where the odour loading increases sharply
in a very short time period the biofilter bacterial population could be negatively
affected. This can lead to reduced odour removal performance biofilters are
therefore more suitable to stable odour loading rates.
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4.1.4 Wet Scrubber and Bio-scrubber
Wet scrubber systems have been used for over one hundred years in air pollution control in
industries such as chemical manufacturing and waste management. A wet scrubber consists
of a number of component parts, namely a vessel which contains media, across which water is
sprayed via recirculation pump, and a fan and ducting system which blows exhaust air in from
the base of the scrubber.
The counter-current mixing of water and air, together with the thin film of water across the
surface of the packing, provides for mass transfer of contaminants from the air into the water,
thereby cleaning the exhaust gas. The wastewater from the scrubber is discharged to sewer
or to a treatment plant and the exhaust air is discharged to atmosphere via a stack.
The key phrase when scrubber operation is referred to is mass transfer”, this is the transfer
of substances from the gas phase (exhaust stream into the scrubber) to the liquid phase (the
scrubber liquid).
The rate of mass transfer is governed by a series of variables, the most significant being:
concentration in the exhaust stream into the scrubber,
surface area of the liquid available,
contact time between exhaust and liquid,
temperature of the liquid, and
concentration of contaminants in the scrubber liquid.
It can readily be seen that these variables explain many of the problems that arise in scrubber
operation, for example:
poor removal rates of contaminants can be due to insufficient contact time (scrubber
too small),
insufficient surface area available (wrong type of packing or insufficient packing
material available), and
insufficient scrubber blowdown (blowdown settings incorrect) leading to build up in
concentration of contaminants in the scrubber liquid (blowdown is water which is
removed from the scrubber unit to keep dissolved solids below setpoint upper limits).
Bio-scrubbers have the same component parts with the addition of biomass in the water, so not
alone does the scrubber remove pollutants from the air, the biomass (composed of micro-
organisms) degrades these pollutants, ensuring their destruction.
Wet scrubbers remove particulates and dissolved gases from an air stream and are therefore
particularly suitable for use where dusty and odorous exhaust streams are present, such as
those at waste transfer stations. Particulates are removed by a process called “impaction”, the
particles of dust or other substances are accelerated in the exhaust stream and impact onto the
water surface on the packing or onto a droplet.
In addition to particulate removal, scrubbers achieve removal of gaseous compounds in the
exhaust stream via absorption of the compounds into the scrubber liquid.
The aim of any scrubber design should be to provide the greatest surface area of liquid available
in a given volume of a scrubber vessel. This surface area is achieved by a combination of
scrubber spray-ball orifice dimensions (which govern droplet site) and Packing Factor, which
indicate the ability of a given type of packing material to provide a given surface area. Both of
these variables must be optimised. If the droplet size is too small relative to the gas velocity,
droplets will tend to get carried out of the discharge from the scrubber, rather than descending
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down onto and through the packing. If packing units are too small the scrubber is likely to block,
especially a bio-scrubber.
Inlet velocities to a scrubber unit should be in the range of 10 30 m/sec, with water velocities
in the region of 0.5 to 2 m/sec.
All wet scrubber designs incorporate mist eliminators or entrainment separators to remove
entrained droplets. The process of contacting the gas and liquid streams results in entrained
droplets, which contain the contaminants or particulate matter. The most common mist
eliminators are chevrons, mesh pads, and cyclones:
Chevrons are simply zig-zag baffles that cause the gas stream to turn several times as
it passes through the mist eliminator. The liquid droplets are collected on the blades of
the chevron and drain back into the scrubber.
Mesh pads are made from interlaced fibres that serve as the collection area.
A cyclone is typically used for the small droplets generated in a venturi scrubber (a
venturi scrubber utilises the energy from the inlet gas stream to atomise scrubber liquid
which increases scrubbing efficiency). The gas stream exiting the venturi enters the
bottom of a vertical cylinder tangentially. The droplets are removed by centrifugal force
as the gas stream spirals upward to the outlet.
Wet scrubbing systems are susceptible to several operating problems. The most common of
these include:
inadequate liquid flow,
liquid re-entrainment,
poor gas-liquid contact,
corrosion, and
plugged nozzles, beds, or mist eliminators.
4.1.4.1 Bio-scrubber
A bio-scrubber unit combines a wet scrubbing unit with a biological reactor, which provides
micro-organisms to biodegrade pollutants in the air exhaust. Bio-scrubbers are used in
industries such as chemical processing, meat or dairy processing, where high concentrations
of amines and ammonia may be present thus it is suited to treatment of air where odorous
compounds are both soluble and biodegradable. Degrees of conversion of over 90% can be
reached in a bio-scrubber for compounds such as ammonia, amines, hydrogen sulfide,
mercaptans, VOC’s and other odorous compounds.
A picture of a typical bio-scrubber is shown in Figure 4.6 below.
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Figure 4.6 An Example Of An Operating Bio-scrubber Unit
Image courtesy of MEHS Ltd.
A high mass transfer rate can be achieved in the scrubber compartment by the high absorption
capacity of the water (i.e. low COD, nitrogen, etc.). In this way both the reactor and the energy
consumption can be reduced. The substrate concentration in the organic phase may be 100 to
1000 times higher than those in the aqueous phase. Thus, in the regeneration compartment
the compounds, which have mainly been absorbed in the organic phase, are transferred to the
aqueous phase where the microbial degradation takes place.
Biological scrubbing of gases to remove odour involve either absorption in a suitable solvent or
chemical treatment with a suitable reagent. It is important that hot, moist streams are cooled
before they contact scrubbing solutions. If this is not done the scrubbing solution will be heated
and become less efficient and the scrubbing medium will become diluted from condensation of
water vapour (temperature of less than 35
o
C).
Biological scrubbing or absorption systems can be either venturi system or packed tower
system. The high-density spray also provides reasonable mass transfer to the absorption of
gaseous contaminants. Bio-scrubber are typically counter current scrubbers that utilize high
surface area media as a contact zone for the gas stream with suitable scrubbing liquor.
The contaminated gas is diffused in the bio-scrubber with the recirculation water and the
bacterial mass and adsorbed onto the biofilm within the packing. This gives microorganisms
the opportunity to degrade the pollutants and to produce energy and metabolic by-products in
the form of CO
2
and H
2
O.
This biological degradation process occurs by oxidation, and can be written as follows:
Organic Pollutant + O
2
CO
2
+ H
2
O + Heat + Biomass
A bio-scrubber consists of two reactors: (a scrubber, and a bioreactor), and also a settling
chamber. In the scrubber, contaminated inlet gas flows through a fine spray of water or water
plus dispersed microbes. The water-soluble contaminants are absorbed out of the gas into the
water or activated-sludge mixture. This contaminant laden water is pumped into the bioreactor.
The cleaned gas is exhausted from the scrubber.
In the bioreactor or activated sludge aeration tank the pollutants are degraded, and the water
is regenerated. Some of the bioreactor liquid is recycled back into the sprayer. Some is sent to
a settling chamber where biomass is settled out. The biomass is returned to the bioreactor and
excess water is sent to a drain. A schematic for the system is shown below in Figure 4.7:
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Figure 4.7 Schematic of a bio-scrubber
Image courtesy of MEHS Ltd.
Of the various biofiltration systems, bio-scrubbers have the least space requirements, the
highest operational stability and process-control, and greatest permeability to gas flow.
Experience has shown that typically, removal rates of 60 - 70% are achievable whereas a
biofilter system can achieve up to 90% removal.
4.1.4.2 Typical Bio-scrubber Design Criteria are as follows:
Air flow rate dependent on loading rate:
Flow rate, 5000 to 30000 m
3
/hr
Loadings 40 140 m
3
/m
2
(dependent on contaminant concentrations)
Contact time 4 - 10 seconds
Amines removal efficiency 85 90%
Ammonia removal efficiency 85 90%
H
2
S removal efficiency 85 90%
VOC removal efficiency 60 80%.
4.1.4.3 Major Design Considerations:
A. Irrigation
The media must be kept moist, but if irrigation is too frequent, the biomass may be deprived of
oxygen. If irrigation is too infrequent, the media can dry out and reduce effectiveness. A
programmable timer may be used to properly time irrigation cycles. The temperature of the
process air is required to be measured during commissioning to establish the cycle.
B. Media
Media should possess high surface area to volume ratios, good adsorption characteristics, low
pressure drop, and good sloughing characteristics. For nitrogen and organic compounds
treatment, media impregnated is seeded with bacteria prior to commissioning.
C. Nutrients
Nutrients must be kept fresh to maintain healthy biomass. Appropriate nutrients essential to the
various bacteria in the bio-scrubber need to be identified. This will be determined prior to
commissioning by sampling and running lab scale tests on samples of the leachate. A dosing
pump is required to allow dosing of nutrients and bacteria selected for particulate odorous
compounds.
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D. Construction materials
Corrosion-resistant materials such as high-density polyethylene (HDPE) are required.
E. Air distribution
Uniform air distribution through the media bed is important for efficient operation. Perforated
fibreglass reinforced plastic (FRP) distribution plates have been used effectively to support the
media bed and distribute the air flow uniformly.
The positives and negatives of scrubbers and bio-scrubbers are shown in Box 14:
Box 14 Positives & Negatives of Wet Scrubbers & Bio-scrubbers
Wet Scrubber
Pro’s
Good particulate removal rates,
Efficient at removing soluble VOCs and other odorous compounds.
Con’s
Wastewater disposal required,
Not good at coping with variable loadings.
Bio-scrubber
Pro’s
Additional removal over and above that of wet scrubber as the biomass provides
a surface onto which some sparingly soluble compounds will more easily adsorb,
Biodegradation of compounds leading to lower strength wastewater,
Ability to cope with variable loadings as biomass provides extra buffering capacity.
Con’s
Requires daily checks for biomass concentration and COD to determine scrubber
health,
This requires training for operators onsite and operator time,
Wastewater disposal required,
Sludge also generated which requires disposal.
While the risk of overloading or shock-loading of the biomass due to a sudden
sharp increase in compounds which the biomass is degrading, is low, it is still a
risk associated with bio-scrubber operation, and regular checks on biomass (using
bacterial counts for example) should be conducted. If a shock-loading or
overloading event occurs which leads to biomass die-off, it may take a number of
weeks to re-seed the bio-reactor and bring the bio-scrubber back on-line.
4.1.5 UV / Ozone / Cold-plasma
In recent years a number of systems for oxidation of odorous compounds within a gas stream
have become available on the market. It is difficult to formulate a single heading for this type
of equipment. At the entry level are ozone generators, which use a high strength electrical
current applied across a narrow gap between graphite electrodes to chemically split the oxygen
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molecule in air and generate ozone gas (O
3
). Oxygen (O
2
) is a stable gas which provides us
with a stable atmosphere to breath and which supports life on earth, ozone is a corrosive toxic
gas which is unstable, and which tends to degrade to O
2
and O
-
radicals. The O
-
radicals are
aggressive atoms which attack organic compounds and oxidise them to non-odorous
components.
The effectiveness of ozone against odorous compounds present in odorous air streams
depends on several factors including:
the amount of ozone applied,
the residual ozone in the air,
the chemistry of the compounds,
the concentration of particles present, and whether the odour attaches to particles or
not,
the smoke content of the emission, and
various environmental factors such as medium pH, temperature, relative humidity,
additives and the amount of organic matter in the air.
Volatile fatty acids and ammonia concentrations are not affected by ozonation to any great
degree.
The next most sophisticated version of these types of equipment uses high voltage UV lamp
arrays to generate a “cold plasma”, which contains ozone and free radicals, but which has a
more comprehensive impact on degrading odorous compounds. These cold plasma units are
used in a range of industries from food processing to chemical manufacturing. Not all odorous
organic compounds are degraded by these systems and a trial is recommended using an onsite
pilot plant, as part of any technology selection process.
The “cold plasma units” have a unique feature whereby the exhaust gas does not pass through
the units. Instead, the units draw in fresh air, which is then “radicalised” and blown into the
exhaust duct where the odorous air is present, and it is here that the oxidation reaction takes
place. This is an advantage for air streams which may contain aerosols of liquid that could
block carbon systems or coat the surface of abatement equipment.
These systems typically only achieve 50 60% odour reduction and are ineffective for some
odours such as smoke from cooking or manufacturing processes but are efficient are degrading
small and more complex organic molecules.
The units tend to be small and compact with a unit the size of a domestic “American fridge”
being sufficient to treat an exhaust stream of 3000 Nm
3
/hour and would have a power
consumption of 30 40 kW. A typical unit is shown below in Figure 4.8. The control panel and
transformer unit used to generate the high voltage for ozone/cold plasma generation is labelled
on Figure 4.8 below, as is the unit which houses filters that remove any dust particles prior to
the plasma generation unit and the fan which draws in clean air and pushes it through the unit
out to the duct where treatment is occurring.
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Figure 4.8 Example Of A Cold Plasma Unit
Image courtesy of Aerox B.V.
The positives and negatives of Cold Plasma Units are shown in Box 15:
Box 15 Positives & Negatives of Cold Plasma Units
Pro’s
Small, compact units,
Relatively low operating cost and low operator input.
Con’s
Destruction rate can be in the region of 50 - 60%,
Not suitable for all odours requires pilot plant testing,
Air streams with dust concentrations tend to soak up the ozone / air mixture (as it
reacts with the dust particles) without much impact on odorous compounds.
4.2 Management Of Abatement Systems
Irrespective of the abatement option chosen, it is important to have in place a system for the
management of the abatement equipment. It is often noted that when abatement systems
experience problems, at the root cause can be a lack of a structured approach to the
management of the system. A person should be appointed to manage the abatement system
on-site and the cost of this person receiving appropriate training on the management of the
system should be included in the manufacturers cost of the installation and commissioning of
the abatement equipment. Training should also be given to a second operative, who can cover
for the first operative if they are not available, this training should be provided by the equipment
supplier also. A management procedure should be prepared which must include:
The daily, weekly or monthly tasks required by the operative during normal and
abnormal operation for abatement plant control and successful operation.
The defined ranges for equipment operating parameters and specific procedures for
what the operative should do if one of the equipment parameters deviates from defined
ranges.
Transformer/
Control Panel
Air Filters &
Fan Unit
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Includes a form for recording deviations from normal operating parameters, which
should record the duration, nature and impact on emissions, the root cause of the
deviation identified and the steps which were taken to eliminate the deviation.
Assurance that the equipment is included in the equipment register for the site.
Linkage to the Management of Change (MoC) procedure for the site which ensures
that any change in the process generating the odours is reviewed for its impact on the
abatement plant and upgrades or changes to the abatement plant are made prior to the
change being made (a MoC procedure is used on a site when there are proposed
changes to site operations, so that the effect of any change on emissions can be
considered and mitigated prior to the change being made).
A reference to the maintenance regime for the system (see below for more detail on
maintenance) including ensuring the equipment is placed on the Preventative
Maintenance Schedule for the site and that all necessary maintenance documentation
is available.
A copy of the Operation and Maintenance Manual for the equipment, as provided by
the supplier. It is very important that the supplier is instructed as part of the contract to
provide an equipment-specific and site-specific O&M manual. It is noted that all too
often much of the O&M manual is generic for a range of plant and it is often not clear
which plant it refers to.
Reference to a Testing and Verification Regime to ensure the plant is operating
correctly and achieving its desired abatement goals before the final equipment
handover.
For older abatement equipment which is already in place to treat odour from a facility,
for which a Testing and Verification Regime may previously not have been developed,
a testing regime should be developed to ensure the performance of the abatement
equipment can be periodically tested against defined limit values. In most cases this
may already be in place as a requirement of the site EPA Licence, but if such a regime
is not in place, one should be developed.
The following flow chart in Figure 4.9 is a useful tool for analysing and documenting a deviation
from normal operating parameters of an abatement plant:
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Figure 4.9 Industrial Process Corrective Action Process Flowchart
Source: Adapted From US EPA Industrial Guide for Air Pollution Control, 625/6-78-004, US EPA, June 1978
4.3 Monitoring Of Abatement Systems
Monitoring of the abatement system will be part of the site’s EPA licence requirements. The key
variables which provide the most reactive and up to date information on an abatement system
should be identified and used to monitor the performance of the abatement system. The
variables used to monitor equipment performance should be listed and the key variables
identified. This should be done in conjunction with the supplier of the equipment, in order to
ensure the correct outcome.
The key variables should be:
Easy to measure (special training or equipment should not be required),
Cost effective to measure - it should be cheap to measure without needing to hire
equipment),
Readily obtainable a result should be obtainable in real-time,
Able to be read from a digital display,
Recordable by data-logger or chart, if not, should be recorded in a log book.
Key variables will vary with the equipment chosen. For example, the bed or chamber
temperature and pressure are key parameters for monitoring a thermal oxidiser unit. If these
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parameters are within the required range values the plant should achieve the target reduction
rate.
For scrubber units the key parameters are pressure difference and static pressure
measurements, for the fan, mist eliminator and scrubber unit. The measurement locations
should be out of the liquid and designed to minimise the risk of scaling or blocking. The
pressure lines should have 3-way valve fittings which would allow compressed air to be purged
through the lines to clear any blockages. For bio-scrubbers, COD and MLSS (Mixed Liquor
Suspended Solids) in the biomass reservoir are important parameters.
With regard to biofilters, pressure drop across the bed and liquid pH are important parameters
and hand-held Draeger units can be used onsite to check for ammonia, hydrogen sulfide and
amines in the treated exhaust. For ozone/cold plasma units, voltage and current flow through
the electrodes or lamps are the critical parameters for determining system status.
If a site BMS (Building Management System) or PCS (Process Control System) is in place, the
key on-line parameters and alarms should be connected to this system, so a deviation can be
immediately notified to personnel. Where a site is unmanned, this may require the BMS or PCS
to send a text or call to a mobile phone, to notify an operator of a deviation.
4.4 Maintenance Requirements Of Abatement Systems
Maintenance can be either Reactive Maintenance (RM) which is a reaction in the event of a
breakdown or malfunction, or Preventative Maintenance (PM) which ensures all equipment is
in the correct condition for operation.
Abatement systems should be placed on the Equipment Register for the site and the PM
requirements including any training required should be determined and agreed as part of
equipment handover prior to final sign off.
The PM regime for the site should have a line item which includes the abatement equipment,
and which lists in an attachment the PM requirements for the equipment. The PM requirements
should be entered onto the site PM regime with the intervals at which each is required. This
should be cross checked and included in final equipment sign off as part of the handover
process before final payment for the equipment.
A site may find that operatives or contractors at the site may not be familiar with the abatement
equipment provided and may require specialist maintenance skills, for both PM and RM. PM
regimes will vary with the type of equipment chosen, as will RM requirements.
It is advisable that a PM / RM contract be signed with the equipment operator for a minimum
12-month period from equipment handover, thus ensuring site operatives are familiar with PM
and RM and are adequately trained in both. The specific tasks which comprise a PM regime
will vary with the type of abatement equipment, but should as a minimum include the following
as shown in Box 16:
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Box 16 Specific Tasks Of A Preventative Maintenance Regime
Taking the unit off-line once per year,
Visually inspect the unit daily; to include all flanges, joints and external units such as
fans,
Note any signs of corrosion, warpage or cracking,
Liquid level (where appropriate) and pressure drop should be checked to determine
if they are within range,
The outlet should be checked for odour in accordance with manufacturer’s
instructions,
The outer shell of the unit should be inspected for signs of deterioration,
Critical parameters (which may be temperature, pH, pressure drop depending on
the equipment) should be checked and recorded and compared to manufacturers
specifications,
On-line monitoring systems should be reviewed to check unit performance over the
previous 24 hours,
Any signs of leaks which may have occurred overnight (staining within bunds for
example) should be recorded and investigated,
Electrical power being drawn by the unit,
All alarms should be checked visually,
Valve positions should be checked to ensure none have been changed.
Weekly checks should include:
Monitoring probes should be checked and recalibrated if required,
Spray bars within scrubber units should be checked for blockages,
Pipes and manifolds should be checked for blockages,
Pressure gauges should be checked for accuracy,
Alarms should be tested to ensure they are electrically energised.
Annual checks will vary with the unit but will generally include taking the unit off-line and
replacing consumables such as seals and filters. Valve seats and other more complex
equipment components may also be checked and replaced, and carbon, scrubber media or
ceramic media may be replaced or cleaned.
It is important that the Annual Check is planned well in advance to ensure all spares, equipment,
tools and personnel are present and available onsite to minimise the down-time for the site
while the abatement system is off-line.
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4.5 Staff Training Requirements
Staff training should be provided by the equipment supplier. At least one staff member should
be trained on the operation, troubleshooting and basic maintenance of the unit, by hands-on
training with the commissioning engineer. A training manual should also be prepared for this
operative which describes their tasks and explains how the system works, some of the faults
which commonly occur and how they can be rectified. This operative should also train at least
one other staff member. Records of training undergone should be kept in the OMP file.
Site maintenance personnel should also be trained by the commissioning engineer, and it is
recommended that the first 12 months maintenance is undertaken by the equipment supplier,
whose team can further train the site maintenance team over that period. The training should
focus on the PM and RM tasks required, how each component of the unit can be maintained
and repaired if required, and how standard lubrication and greasing should be undertaken.
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5.0 TEST PROGRAMMES FOR ODOUR ABATEMENT EQUIPMENT
Where abatement is required, a test programme may be obligated as outlined in the example
below from a current IE Licence (for a waste facility):
Test Programme Requirements (Example Text):
The licensee shall prepare, to the satisfaction of the Agency, a test programme for
(a) abatement equipment installed to control odour / dust emissions from the Waste
Recovery Buildings and (b) the biodiesel production equipment. Each test programme
shall be submitted to the Agency, prior to implementation.
Each programme, following agreement with the Agency, shall be completed within
three months of commencement of operation of the equipment
The criteria for the operation of the odour / dust abatement equipment and biodiesel
production equipment as determined by the respective test programmes, shall be
incorporated into the standard operating procedures as approved by the Agency.
Each test programme, referred to above, shall as a minimum: -
Establish all criteria for operation, control and management of the equipment to
ensure compliance with the requirements of this licence and
Assess the performance of any monitors on the abatement system/s and
establish a maintenance and calibration programme for each monitor.
A report on each test programme shall be submitted to the Agency within one month of
completion”.
5.1 Monitoring Of Odour Abatement Effectiveness
Once abatement equipment is newly installed on an existing site or if a site is newly licensed
and already has pre-installed abatement equipment on it, the site operator must demonstrate
that equipment is suitable and capable for use to meet the abatement targets set for the
equipment. In order to demonstrate this, a test programme should be developed which explains
how the site operator proposes to prove the abatement equipment’s suitability and capability to
meet the abatement targets.
The test programme should also ensure that the site operator can assess the performance of
any monitoring equipment used on the abatement system and establish a maintenance and
calibration programme for each equipment item. Additionally, the test programme should also
assess the performance of any monitors on the abatement system/s and establish a
maintenance and calibration programme for each monitor. The test programme for any piece
of abatement equipment is not just limited to how that item operates in isolation; rather its impact
on other plant and equipment must also be assessed.
The equipment items which are part of the abatement system will have the following functions:
Controlling,
Measuring,
Monitoring.
Each of these equipment items will have to be examined as part of the test programme and be
deemed fit for purpose. Any monitor (for example thermocouple, flow meter, flue gas analyser)
should also be capable of operating across the performance range in which the abatement
equipment is being tested.
As a consequence of the manner in which these related items perform during the test
programme, a test programme must ensure that the equipment is maintained and calibrated so
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that changes in the abatement equipment do not have an adverse or an unknown impact on
the relevant monitors.
A documented maintenance and calibration programme (including a schedule), for any monitor
associated with the abatement equipment is an essential part of the test programme.
The criteria for the operation of the abatement equipment as determined by the test programme,
should be incorporated into the standard operating procedures (SOPs) by the site operator once
the abatement system is commissioned and fully operational.
The findings of the completed test programme should be recorded and implemented. All
relevant SOPs should, following the completion of the test programme, be updated to account
for the knowledge gained from assessing the results obtained from the test programme.
5.2 Template For A Test Programme
The template for a test programme is provided in Appendix C of this document. The test
programme shall as a minimum establish all criteria for operation, control and management of
the abatement equipment to ensure compliance. A successfully completed test programme
should provide the operator with the knowledge of how best to operate, control and manage
the relevant abatement equipment in order to comply with the requirements of the abatement
targets.
The programme should include reference to the Manufacturers requirements for maintenance,
operational procedures and training requirements and describes how the Operator will ensure
compliance with these requirements.
5.2.1 Acceptance of Test Programme Output
The test programme should define the criteria for determining when system performance will
be deemed to be acceptable, for example it should include the statement:
Abatement system performance will be deemed to be acceptable if over the two-month period:
All emission limit values (ELVs) defined for the abatement equipment are met on each
monitoring occasion and if a CEMS unit is installed, for the CEMS Unit for those
parameters measured:
Concentration limit values,
Volumetric flow rate.
There are no emission limit values for the following parameters, but it is important to
measure these parameters and compare with design criteria:
Velocity,
Pressure,
Temperature,
Oxygen content (where relevant),
Water content (where relevant).
And (for the following continuously recorded parameters):
System design temperature in the combustion chamber (for thermal oxidisers),
System design retention time shall be met at all times,
Pressure drop across bed or abatement system,
Voltage or current across electrodes,
Scrubber conductivity (where relevant) shall remain within set point values at all times.
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For thermal oxidisers the test programme should also include defining reference oxygen
concentration. Testing before and after the abatement equipment should be undertaken to
check if the abatement unit is experiencing the loadings for which it was designed and to
determine if the removal efficiency is as per the design criteria.
5.3 Maintenance, Operation and Training to be Documented in Test Programme
The supplier of the abatement equipment must ensure that site personnel receive appropriate
training on the maintenance and operation of the system prior to the two-month test programme
commencing.
The supplier must ensure that at the end of the training programme sufficient personnel have
been trained in how to maintain and operate the Abatement System such that criteria defined
for the abatement system can be met.
5.3.1 CEMS System
This should include training in how to operate and maintain the CEMS system and the
associated Data Acquisition and Handling System it is accepted that a specialist maintenance
external contractor may maintain and test the CEMS unit. The air emissions monitoring
undertaken should also focus on verification that the CEMS unit is operating correctly.
5.3.2 Alarms
CEMS unit alarm, temperature and flow alarms are set to trigger at 75% of the relevant ELV
(Emission Limit Value) and when 90% is reached a signal is sent to production to begin shut-
down of the manufacturing process. Alarms need to be visual and audible, the CEMS system
should link to the site SCADA (Supervisory Control And Data Acquisition) system. Alarms could
include text or email alerts to key personnel if 24-hour supervision is unavailable onsite.
5.3.3 Calibration
Calibration should be carried out as per the instrument list issued by the equipment supplier.
Calibration certificates and labels should be produced for each instrument calibrated.
Calibration gases (calibration gases are marked with a date after which they should not be used
the gases used should be within date) and calibration certificates for each calibration gas
should also be provided.
Training in Preventative Maintenance should include:
Replace consumables where necessary (usually filter elements where cleaning will not
suffice).
Test the operation of individual items in each of the systems, such as the chiller, sample
pumps, moisture switch, flow switch.
Ensure all alarms operate correctly and are indicated where applicable.
Complete a visual inspection for loose fittings, ingress of moisture and general wear
and tear.
The following should also be completed as part of maintenance:
Back-ups to be made of all data files.
Back-ups to be made of the system software every six months.
Reports system to be tested.
General software and hardware maintenance.
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6.0 REFERENCES
Alliance. Clean Air Strategic (2015). Odour And Health Backgrounder (Version 19).
Belgiomo. (2013). Odour Impact Assessment Handbook.
Cooper&Alley. (2011). Air Pollution Control - A Design Approach, 4th Edition.
DEFRA. (2010). Odour Guidance for Local Authorities.
EA. (2011). H4 Odour Management.
EC. (2005). Reference Document on Best Available Techniques in the Slaughterhouses and Animal
By-products Industries .
EC. (2016). BAT Conclusions for the Common Waste Water & Waste Gas Treatment Management
Systems in the Chemical Sector.
EC. (2016). BAT Reference Document for Common Waste Water and Waste Gas
Treatment/Management Systems in the Chemical Sector.
EC. (2017). Best Available Techniques (BAT) Reference Document for the Intensive Rearing of
Poultry or Pigs (IRPP BREF).
EC. (2017). Commission Implementing Decision (EU) 2017/302 established BAT Conclusions, Under
Directive 2010/75/EU, for The Intensive Rearing of Poultry or Pigs.
EC. (2018). BAT Reference Document in the Food, Drink and Milk Industries ((Final Draft).
EC. (2018). Best Available Techniques (BAT) Reference Document for Waste Treatment.
EPA. (2001). Odour Impacts & Odour Emission Control Measures for Intensive Agriculture.
EPA. (2010). Air Dispersion Modelling from Industrial Installations Guidance Note (AG4).
EPA. (2018). Emissions Monitoring Guidance Note.
EPA. (2018). EPA Industrial And Waste Licence Enforcement 2017.
EPA. (2019). Odour Impact Assessment Guidance for EPA Licensed Sites (AG5).
Harreveld, A. V. (2001). From Odorant Formation to Odour Nuisance: New Definitions for Discussing
a Complex Process. Water Science & Technology.
Heaney. (2011). Relation between malodor, ambient hydrogen sulfide, and health in a community
bordering a landfill. Environ Res., 111(6): 847-852.
Horton. (2009). Malodor as a Trigger of Stress & Negative Mood in Neighbors of Industrial Hog
Operations. American Journal of Public Health, Supplement 3, Vol 99 No. 53 P. S610.
IAQM. (2014). Guidance On The Assessment Of Odour For Planning.
Laor. (2014). Measurement, prediction, and monitoring of odors in the environment: A critical review.
Rev Chem Eng, 30(2) 139 - 166.
NSW, D. (2006). Assessment And Management of Odour From Stationary Sources In NSW.
NZMFE. (2016). Good Practice Guide For Assessing And Managing Odour.
Schenk. (2009). "Fact Sheets On Air Emission Abatement Techniques", Information Centre for
Environmental Licensing, The Hague, 2009.
Schinasi. (2011). Air Pollution, Lung Function and Physical Symptoms in Communities Near
Concentrated Swine Feeding Operations. Epidemiology, 22(2): 208 - 215.
SEPA. (2010). Odour Guidance 2010.
Suffet. (2009). Sensory Assessment and Characterisation of Odor Nuisance Emissions during the
Composting of Wastewater Biosolids.
Tajik. (2008). Impact of Odor From Industrial Hog Operations On Daily Living Activities. New
Solutions, Vol. 18(2) 193-205.
Yang, H. &. (2000). Odour Nuisance - advantages and disadvantages of a quantitative approach.
Water Science & Technology, Vol. 41 No.6 Pages 97 - 106.
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APPENDIX A Odour Complaint Report Form
ODOUR COMPLAINT REPORT FORM
Name & Address:
Phone Number:
Time / Date of Complaint:
Time / Date of Odour:
Location of Odour:
Weather Conditions:
Dry
Rained Recently
Drizzle
Raining
Foggy
Temperature:
Cold
Cool
Warm
Hot
Wind
Strength:
Calm
Light
Air
Light
Breeze
Gentle
Breeze
Moderate
Breeze
Fresh
Breeze
Strong
Breeze
Near
Gale
Gale
Strong
Gale
Type of Odour (see below):
Odour Intensity (see below):
Persistence Scale (see below):
Duration of Odour (time):
Nature of Exposure:
No Odour
Intermittent
Persistent
Any Comments /
Additional Information:
Type Of Odour
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APPENDIX B Odour Management Plan Checklist
Odour Management Plan Checklist
Name of Activity:
Date:
Process Description / Potential Odorous Activities:
Approved By:
Checklist
( - on
completion)
Comments
Details of Sensitivity of Local Environment:
Map of Site & Local Receptors / Meteorological Factors
(Source-Pathway-Receptors Concept):
Legal Framework / Licence Conditions:
Management Structure:
Designation of Responsibility for Compiling Odour
Management Plan:
Process Flow Diagram Detailing Odour Sources / Release
Points:
Odour
Sources /
Pathways
Raw
Materials /
Inventory
Equipment
Processes
&
Activities
Release
Points
Finished
Products
Wastes
Imports /
Exports
Routine
Methods /
Control
Measures:
Assigned To:
Planned
Maintenance
& Repair
Schedule:
Assigned To:
Emergency
Incidents /
Accidents
Measures:
Assigned To:
Checklist
( - on
completion)
Comments
Odour Impact Assessment Survey Protocol:
Odour Complaint Log Protocol:
Community Liaison Protocol:
Review Process / Audit Timetable:
Record Keeping:
Comments:
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APPENDIX C Test Programme Checklist
Test Programme Checklist
Name of Activity:
Date:
Odour Abatement Process Description (attach a Process Flow
Diagram with explanatory text of the odorous processes including
key characteristics of odorous exhaust and abatement design):
Approved By:
Checklist
(√ - on
completion)
Comments
Emissions monitoring conducted on 3 occasions over the
duration of the test programme?
System retention time met at all times?
Combustion temperature achieved at all times (if
relevant)?
Pressure drop across system within range at all times?
Voltage/current within range at all times? (if relevant)
Conductivity in scrubber within range at all times (if
relevant)
Velocity and flow rate through unit measured?
Oxygen content of exhaust measured? (if relevant)
Water content of exhaust measured? (if relevant)
Did any deviations from standard operating parameters
occur during the test programme period? (If so please
describe on a separate sheet and explain how they were
investigated, what was the outcome and how were they
rectified).
Describe the criteria the unit has to meet to pass the Test
Programme and have these been achieved? (Provide
evidence on a separate sheet and attach).
Comments:
The duration of the Test Programme should be agreed with the EPA in advance of the
implementation of the test programme from the date of completion of commissioning by the
equipment supplier. The Abatement System should be subject to the loads normally seen from
the manufacturing process, over the test programme period. Emissions monitoring upstream
of the abatement unit and downstream of the abatement unit should be conducted by an ISO
17025 accredited Air Emissions Monitoring Team, on three occasions over the testing period
with a comparison undertaken with the target values defined for the abatement equipment.
Any deviations from these target values noted during this testing programme should be
investigated and subject to Root Cause Analysis. The fault shall be identified and remedied
and the testing re-done once the fault is remedied. The monitoring should be undertaken
following Irish EPA Guidance (AG2 - Emissions Monitoring Guidance Note) (EPA, 2018) and
other appropriate guidance as agreed with the EPA.
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APPENDIX D Glossary of Terms
Adaptation
Temporary modification of the sensitivity of the human nose due to
continued and/or repeated stimulation
Aerobic Processes
Biological processes that occur in the presence of oxygen
Anaerobic Processes
Biological processes that occur in the absence of any common electron
acceptor such as nitrate, sulfate or oxygen
Anoxic Processes
Biological processes that occur in the presence of electron acceptors
such as nitrate or sulfate, while oxygen is absent
Advanced models:
Dispersion models that are based on modern scientific theories and
complex mathematical formulations. They can assess multiple sources,
complex terrain and detailed meteorological conditions.
Biodegradability
Extent to which an organic substance can be degraded by
microorganisms under specified conditions. Biodegradability is usually
expressed as a percentage of the substance degraded.
Dynamic Dilution
Olfactometry
A technique which determines the odour concentration based on the
number of dilutions with neutral air that are necessary to bring the
odorous sample to its odour detection threshold concentration.
Detection Threshold
The concentration at which an odorous chemical or mixture can be just
detected.
EHS
Environmental, Health & Safety
End-of-pipe technique
A technique that reduces the final emission level, but which does not
change the fundamental operation of the core process.
Intensity
An assessment of odour strength, based on a logarithmic scale, ranging
from no odour to extremely strong odour.
Odour Concentration
The concentration of an odorant mixture is defined as the dilution factor
to be applied to an effluent in order to be no longer perceived as odorant
by 50% of people in a sample of the population. The odour concentration
at the limit of detection is by definition 1 OU
E
/m
3
.
Odour Intensity
Value of the perception for a stimulus above the corresponding detection
threshold. The odour intensity is determined by a sample of persons by
comparing the odour perception level in the effluent with samples of an
odorant reference (n-butanol at different levels of dilution).
Odour Threshold
The limiting concentration of a substance in air below which its odour is
not perceptible
Olfactory Fatigue
Associated only with H
2
S. At concentration of greater than about
100ppm, H
2
S causes paralysis of nerves in the nose leading to complete
but temporary loss of smell.
Recognition Threshold
The concentration at which the specific odour can be recognised,
typically 3-5 times the odour detection threshold.